2H-Heptafluorobut-2-ene as a synthon for hexafluorobut-2-yne

被引：8

作者：

Chambers, RD

Roche, AJ

机构：

[1] Department of Chemistry, University of Durham, Durham DH1 3LE, South Road

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1996年 / 79卷 / 02期

关键词：

heptafluorobut-2-ene; hexafluorobut-2-yne;

D O I：

10.1016/S0022-1139(96)03448-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of heptafluorobut-2-ene with nucleophiles are described, in some cases giving products analogous to those previously obtained from hexafluorobut-2-yne. Depending on the conditions, hydrolysis can lead to 1,1,1,4,4,4-hexafluorobutan-2-one, or 1,1,1-trifluoroacetone. Reactions with diols, bis-phenols, ammonia and amines are also described.

引用

页码：139 / 143

页数：5

共 10 条

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