L-lysine-L-tartaric acid: New molecular complex with nonlinear optical properties. Structure, vibrational spectra and phase transitions

被引：60

作者：

Debrus, S

Marchewka, MK

Baran, J

Drozd, M

Czopnik, R

Pietraszko, A

Ratajczak, H

机构：

[1] Univ Paris 06, CNRS, UMR 7601, Lab Opt Solides, F-75015 Paris, France

[2] Polish Acad Sci, Inst Low Temp & Struct Res, PL-50950 Wroclaw, Poland

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2005年 / 178卷 / 09期

关键词：

lysine; tartrates; hydrogen bond; phase transitions; FTRaman; FTIR; structure-spectra correlation; incommensurate phase; second harmonic generation;

D O I：

10.1016/j.jssc.2005.06.029

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

The first X-ray diffraction and vibrational spectroscopic analysis of a novel complex between L-lysine and L-tartaric acid is reported. The structure was solved in two temperatures (320 and 260 K) showing incommensurate phase between them. Room-temperature powder infrared and Raman measurements for the L-lysine-L-tartaric acid molecular complex (1: 1) were carried out. DSC measurements on powder samples indicate two phase transitions points at about 295, 300 and 293, 300K, for heating and cooling, respectively, with noticeable temperature interval between them. Second harmonic generation efficiency d(eff) = 0.35 d(eff) (KDP). (c) 2005 Elsevier Inc. All rights reserved.

引用

页码：2880 / 2896

页数：17

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