Oxidative coupling of porphyrins using copper(II) salts

被引：35

作者：

Brennan, Bradley J. ^{[1
]}

Kenney, Michael J. ^{[1
]}

Liddell, Paul A. ^{[1
]}

Cherry, Brian R. ^{[2
]}

Li, Jian ^{[3
]}

Moore, Ana L. ^{[1
]}

Moore, Thomas A. ^{[1
]}

Gust, Devens ^{[1
]}

机构：

[1] Arizona State Univ, Dept Chem & Biochem, Ctr Bioenergy & Photosynth, Tempe, AZ 85287 USA

[2] Arizona State Univ, Magnet Resonance Res Ctr, Tempe, AZ 85287 USA

[3] Arizona State Univ, Sch Mat, Tempe, AZ 85284 USA

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 36期

关键词：

COMPLEXES; ROTATION; ABSORPTION;

D O I：

10.1039/c1cc13596a

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

A method for radical coupling of porphyrins using copper(II) salts as one-electron oxidants was developed. A Zn(II)-porphyrin bearing an aminophenyl group yielded porphyrin oligomers, and two tri-arylporphyrins were oxidized to form doubly and triply linked dimers. Bromination of doubly linked dimers gave macrocycles with twisted skeletons.

引用

页码：10034 / 10036

页数：3

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