Electrocatalysis for Polymer Electrolyte Fuel Cells: Recent Achievements and Future Challenges

被引：707

作者：

Rabis, Annett ^{[1
]}

Rodriguez, Paramaconi ^{[1
]}

Schmidt, Thomas J. ^{[1
,2
]}

机构：

[1] Paul Scherrer Inst, Gen Energy Res Dept, Electrochem Lab, CH-5232 Villigen, Switzerland

[2] Swiss Fed Inst Technol, Phys Chem Lab, Electrochem Grp, CH-8093 Zurich, Switzerland

来源：

ACS CATALYSIS | 2012年 / 2卷 / 05期

关键词：

electrocatalysis; fuel cell; oxygen reduction reaction; alcohol oxidation; OXYGEN REDUCTION REACTION; FE-BASED CATALYSTS; ETHANOL ELECTROOXIDATION REACTION; SUPPORTED COSE2 NANOPARTICLES; SINGLE-CRYSTAL SURFACES; SMALL ORGANIC-MOLECULES; THIN-FILM CATALYSTS; X-RAY-SCATTERING; TUNGSTEN CARBIDE; PARTICLE-SIZE;

D O I：

10.1021/cs3000864

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Fuel cell technology is currently shifting very fast from fundamental research to real development. In addition to other aspects, this transition is possible because of the important improvements achieved in the field of electrocatalysis in the past decade. This perspective will give a focused overview summarizing the most outstanding contributions in the last 10 years in terms of activity and durability of the catalyst materials for ethanol oxidation and oxygen reduction reaction, respectively. In addition, it provides an outlook about new catalyst support materials with improved performance/stability, advanced characterization techniques, and fundamental studies of reaction mechanisms and degradation processes. All the studies referred to in this perspective significantly contribute to reaching the technical targets for PEFC commercialization.

引用

页码：864 / 890

页数：27

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