Quinacridone-Based Electron Transport Layers for Enhanced Performance in Bulk-Heterojunction Solar Cells

被引:49
作者
Pho, Toan V. [1 ,2 ]
Kim, Heejoo [1 ,2 ]
Seo, Jung Hwa [1 ,2 ]
Heeger, Alan J. [1 ,2 ]
Wudl, Fred [1 ,2 ]
机构
[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
[2] Univ Calif Santa Barbara, Ctr Polymers & Organ Solids, Santa Barbara, CA 93106 USA
基金
美国国家科学基金会;
关键词
INJECTION;
D O I
10.1002/adfm.201101257
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A water/alcohol-soluble small molecule based on the commercially available pigment quinacridone is employed as an electron transport layer in organic photovoltaics. The quinacridone derivative is utilized in solution-processed bulk-heterojunction solar cells to improve primarily the fill factor of the devices, contributing to an upwards of 19% enhancement in the power conversion efficiency relative to the control devices with no electron transport layer. The facile synthesis of the quinacridone derivative coupled with the ease of device fabrication via solution processing provide a simple, yet effective means of improving the performance of existing organic photovoltaic cells.
引用
收藏
页码:4338 / 4341
页数:4
相关论文
共 25 条
[1]   Device physics of polymer:fullerene bulk heterojunction solar cells [J].
Blom, Paul W. M. ;
Mihailetchi, Valentin D. ;
Koster, L. Jan Anton ;
Markov, Denis E. .
ADVANCED MATERIALS, 2007, 19 (12) :1551-1566
[2]   A low-bandgap poly(2,7-carbazole) derivative for use in high-performance solar cells [J].
Blouin, Nicolas ;
Michaud, Alexandre ;
Leclerc, Mario .
ADVANCED MATERIALS, 2007, 19 (17) :2295-+
[3]   Effect of LiF/metal electrodes on the performance of plastic solar cells [J].
Brabec, CJ ;
Shaheen, SE ;
Winder, C ;
Sariciftci, NS ;
Denk, P .
APPLIED PHYSICS LETTERS, 2002, 80 (07) :1288-1290
[4]   Polymer-Fullerene Bulk-Heterojunction Solar Cells [J].
Dennler, Gilles ;
Scharber, Markus C. ;
Brabec, Christoph J. .
ADVANCED MATERIALS, 2009, 21 (13) :1323-1338
[5]   High performance polythiophene/fullerene bulk-heterojunction solar cell with a TiOx hole blocking layer [J].
Hayakawa, Akinobu ;
Yoshikawa, Osamu ;
Fujieda, Takuya ;
Uehara, Kaku ;
Yoshikawa, Susumu .
APPLIED PHYSICS LETTERS, 2007, 90 (16)
[6]   Origin of the enhanced open-circuit voltage in polymer solar cells via interfacial modification using conjugated polyelectrolytes [J].
He, Chao ;
Zhong, Chengmei ;
Wu, Hongbin ;
Yang, Renqiang ;
Yang, Wei ;
Huang, Fei ;
Bazan, Guillermo C. ;
Cao, Yong .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (13) :2617-2622
[7]   Electron injection into organic semiconductor devices from high work function cathodes [J].
Hoven, Corey V. ;
Yang, Renqiang ;
Garcia, Andres ;
Crockett, Victoria ;
Heeger, Alan J. ;
Bazan, Guillermo C. ;
Nguyen, Thuc-Quyen .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2008, 105 (35) :12730-12735
[8]   Stability/degradation of polymer solar cells [J].
Jorgensen, Mikkel ;
Norrman, Kion ;
Krebs, Frederik C. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2008, 92 (07) :686-714
[9]   Increased open-circuit voltage in bulk-heterojunction solar cells using a C60 derivative [J].
Kim, Heejoo ;
Seo, Jung Hwa ;
Park, Eun Young ;
Kim, Tae-Dong ;
Lee, Kwanghee ;
Lee, Kwang-Sup ;
Cho, Shinuk ;
Heeger, Alan J. .
APPLIED PHYSICS LETTERS, 2010, 97 (19)
[10]   New architecture for high-efficiency polymer photovoltaic cells using solution-based titanium oxide as an optical spacer [J].
Kim, JY ;
Kim, SH ;
Lee, HH ;
Lee, K ;
Ma, WL ;
Gong, X ;
Heeger, AJ .
ADVANCED MATERIALS, 2006, 18 (05) :572-+