Bis(isonicotinato)iron(II): a rare, neutral three-dimensional iron coordination polymer

被引：70

作者：

Xiong, RG

Wilson, SR

Lin, WB ^{[1
]}

机构：

[1] Brandeis Univ, Dept Chem, Waltham, MA 02454 USA

[2] Univ Illinois, Sch Chem Sci, Urbana, IL 61801 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 24期

关键词：

D O I：

10.1039/a806499g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of iron(III) perchlorate with 4-pyridinecarbaldehyde under hydro(solvo)thermal conditions affords bis(isonicotinato)iron(II) 1, in which both pyridine and carboxylate groups coordinate to iron centers resulting in an unprecedented neutral, three-dimensional polymeric network with a carboxylate-bridged Fe-Fe infinite chain.

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页码：4089 / 4090

页数：2

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