A water soluble, recyclable organostannatrane

被引：18

作者：

Han, XJ ^{[1
]}

Hartmann, GA ^{[1
]}

Brazzale, A ^{[1
]}

Gaston, RD ^{[1
]}

机构：

[1] So Illinois Univ, Dept Chem & Biochem, Carbondale, IL 62901 USA

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 34期

关键词：

D O I：

10.1016/S0040-4039(01)01148-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Synthesis of a water-soluble recyclable organostannatrane has been accomplished via a straightforward three-step synthesis. The organostannatrane exhibits excellent water-solubility (0.33 M) and can be recovered from aqueous solutions via removal of water in vacuo. The compound can be readily converted by standard transformations into reagents suitable for Stille cross-coupling reactions. The reagent can also be transformed into a reactive, water-soluble organotin hydride. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：5837 / 5839

页数：3

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