Kinetically controlled, shape-directed assembly of nanorods

被引：38

作者：

Ciszek, Jacob W. ^{[1
,2
]}

Huang, Ling ^{[1
,2
]}

Wang, Yuhuang ^{[1
,2
]}

Mirkin, Chad A. ^{[1
,2
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Northwestern Univ, Int Inst Nanotechnol, Evanston, IL 60208 USA

来源：

SMALL | 2008年 / 4卷 / 02期

关键词：

kinetics; nanorods; self-assembly; superstructures; templates;

D O I：

10.1002/smll.200700840

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A method for assembling many individual segmented nanorods into superstructures with control over size and shape under same environmental conditions, was investigated. A lithographically generated form is printed on a template that defines the footprint and number of rods, which can be used assembly process. Segmented nanorods, made up of gold and polypyrole (Ppy), was prepared by the porous alumina template deposition process. Photolithography applied to alumina was used to generate multiwalled DNA extraction systems and patterned arrays of rods immobilized in orientations on solid substrates. Energy-dispersive X-ray spectroscopy was used to examine the removal of silver from the process. Optical microscopy in association with atomic force microscopy (AFM) allows more definitive statements regarding the assembly mechanism.

引用

页码：206 / 210

页数：5

共 34 条

[1]

Brinker CJ, 1999, ADV MATER, V11, P579, DOI 10.1002/(SICI)1521-4095(199905)11:7<579::AID-ADMA579>3.3.CO

[2]

2-I

[3] MATERIALS SCIENCE - SYNTHETIC-POLYMER SELF-ASSEMBLY [J].

CALVERT, P .

NATURE, 1987, 326 (6113) :540-540

[4] Metal-directed self-assembly of two- and three-dimensional synthetic receptors [J].

Fujita, M .

CHEMICAL SOCIETY REVIEWS, 1998, 27 (06) :417-425

[5]

Gracias DH, 2002, ADV MATER, V14, P235, DOI 10.1002/1521-4095(20020205)14:3<235::AID-ADMA235>3.0.CO

[6]

2-B

[7] Self-assembly and mineralization of peptide-amphiphile nanofibers [J].

Hartgerink, JD ;

Beniash, E ;

Stupp, SI .

SCIENCE, 2001, 294 (5547) :1684-1688

[8]

Holliday B. J., 2001, ANGEW CHEM, V113, P2076

[9]

Holliday BJ, 2001, ANGEW CHEM INT EDIT, V40, P2022, DOI 10.1002/1521-3773(20010601)40:11<2022::AID-ANIE2022>3.0.CO

[10]

2-D

← 1 2 3 4 →