Coordinatively unsaturated ruthenium allenylidene complexes:: highly effective, well defined catalysts for the ring-closure metathesis of α,ω-dienes and dienynes

被引：171

作者：

Fürstner, A ^{[1
]}

Hill, AF

Liebl, M

Wilton-Ely, JDET

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

[2] Univ London Imperial Coll Sci Technol & Med, Dept Chem, Ctr Chem Synth, London SW7 2AY, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 07期

关键词：

D O I：

10.1039/a900187e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The well defined, conveniently accessible and coordinatively unsaturated allenylidene complexes [RuCl2(=C=C=CPh2)(PCy3)(2)] and [Ru2Cl4(=C=C=CPh2)(PCy3)(eta-MeC6H4Pri-4)] are highly effective catalysts for the ambient temperature ring-closure metathesis of alpha,omega-dienes and dienynes, illustrated by the facile and high yielding formation of variously functionalised 5, 6, 7, 8, 15, 16 and 18 membered mono- and bi-cyclic ring systems.

引用

页码：601 / 602

页数：2

共 13 条

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