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Miscibility and phase behavior of water-dicarboxylic acid type ionic liquid mixed systems
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作者:

Fukaya, Yukinobu
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Tokyo Univ Agr & Technol, Koganei, Tokyo 1848588, Japan Tokyo Univ Agr & Technol, Koganei, Tokyo 1848588, Japan

Sekikawa, Kenta
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Tokyo Univ Agr & Technol, Koganei, Tokyo 1848588, Japan Tokyo Univ Agr & Technol, Koganei, Tokyo 1848588, Japan

Murata, Kenichi
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Tokyo Univ Agr & Technol, Koganei, Tokyo 1848588, Japan Tokyo Univ Agr & Technol, Koganei, Tokyo 1848588, Japan

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[1] Tokyo Univ Agr & Technol, Koganei, Tokyo 1848588, Japan
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D O I:
10.1039/b704992g
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Tetra-n-butylphosphonium type ionic liquids with fumarate anion and maleate anion exhibit different physico-chemical properties and different solubility to water in their cis and trans conformations; fumarate showed the usual upper critical solution temperature (UCST) behavior, whereas maleate had highly unusual lower critical solution temperature (LCST) behavior after mixing with water.
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页码:3089 / 3091
页数:3
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