Miscibility and phase behavior of water-dicarboxylic acid type ionic liquid mixed systems

被引:55
作者
Fukaya, Yukinobu [1 ]
Sekikawa, Kenta [1 ]
Murata, Kenichi [1 ]
Nakamura, Nobuhumi [1 ]
Ohno, Hiroyuki [1 ]
机构
[1] Tokyo Univ Agr & Technol, Koganei, Tokyo 1848588, Japan
关键词
D O I
10.1039/b704992g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Tetra-n-butylphosphonium type ionic liquids with fumarate anion and maleate anion exhibit different physico-chemical properties and different solubility to water in their cis and trans conformations; fumarate showed the usual upper critical solution temperature (UCST) behavior, whereas maleate had highly unusual lower critical solution temperature (LCST) behavior after mixing with water.
引用
收藏
页码:3089 / 3091
页数:3
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