Heptamethine cyanine dyes with a large stokes shift and strong fluorescence: A paradigm for excited-state intramolecular charge transfer

被引：511

作者：

Peng, XJ ^{[1
]}

Song, FL ^{[1
]}

Lu, E ^{[1
]}

Wang, YN ^{[1
]}

Zhou, W ^{[1
]}

Fan, JL ^{[1
]}

Gao, YL ^{[1
]}

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 12期

关键词：

D O I：

10.1021/ja043413z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New heptamethine cyanine dyes with an alkylamino group at the central position were found to exhibit a large Stokes shift (>140 nm) and strong fluorescence. They were suggested to be a new paradigm for excited-state intramolecular charge transfer (ICT). The configuration change of the bridgehead amine accompanying ICT was investigated in different viscosity and pH media. Copyright © 2005 American Chemical Society.

引用

页码：4170 / 4171

页数：2

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