学术探索
学术期刊
新闻热点
数据分析
智能评审

New diketo-pyrrolo-pyrrole (DPP) sensitizer containing a furan moiety for efficient and stable dye-sensitized solar cells

被引：123
作者：
Qu, Sanyin
Wang, Bing
Guo, Fuling
Li, Jing
Wu, Wenjun [1 ]
Kong, Cong
Long, Yitao
Hua, Jianli
机构：
[1] E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China
来源：
DYES AND PIGMENTS | 2012年 / 92卷 / 03期
关键词：
Diketo-pyrrolo-pyrrole; Metal-free; Dye-sensitized solar cell; Furan; Ionic liquid electrolyte; Stability; FREE ORGANIC-DYES; NANOCRYSTALLINE TIO2 FILMS; MOLECULAR DESIGN; CYANINE DYE; PHOTOSENSITIZER; PERFORMANCE; THIOPHENE;
D O I：
10.1016/j.dyepig.2011.09.009
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A new metal-free organic sensitizer containing a furan moiety as the pi-spacer based on the diketo-pyrrolo-pyrrole unit was synthesized through simple synthetic routes and with low cost for the application of dye-sensitized solar cells. Two corresponding dyes with benzene and thiophene spacers were also synthesized for the purpose of comparison. On the basis of optimized DSSC test conditions, the sensitizer containing the furan shows prominent solar energy conversion efficiency (eta) of 5.65% (J(SC) = 15.96 mA cm(-2), V-OC = 541 mV, ff = 0.65) under simulated full sunlight irradiation. The dyes were also tested in a solvent-free ionic liquid electrolyte devices and the stability of devices was performed over 2000 h at full sunlight. The sensitizer containing the furan moiety exhibited good stability and better photovoltaic performance of up to 4.41% power conversion efficiency. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1384 / 1393
页数：10
相关论文
共 54 条
[1]   Molecular design of metal-free D-π-A substituted sensitizers for dye-sensitized solar cells [J].
Alibabaei, L. ;
Kim, J. -H. ;
Wang, M. ;
Pootrakulchote, N. ;
Teuscher, J. ;
Di Censo, D. ;
Humphry-Baker, R. ;
Moser, J. -E. ;
Yu, Y. -J. ;
Kay, K. -Y. ;
Zakeeruddin, S. M. ;
Graetzel, M. .
ENERGY & ENVIRONMENTAL SCIENCE, 2010, 3 (11) :1757-1764
[2]   Small band gap copolymers based on furan and diketopyrrolopyrrole for field-effect transistors and photovoltaic cells [J].
Bijleveld, Johan C. ;
Karsten, Bram P. ;
Mathijssen, Simon G. J. ;
Wienk, Martijn M. ;
de Leeuw, Dago M. ;
Janssen, Rene A. J. .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (05) :1600-1606
[3]   α-Oligofurans: Molecules without a Twist [J].
Bunz, Uwe H. F. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (30) :5037-5040
[4]  
Gao FF, 2008, CHEM COMMUN, P2635, DOI 10.1039/b802909a
[5]   Dye-sensitized solar cells: A safe bet for the future. [J].
Goncalves, Luis Moreira ;
Bermudez, Veronica de Zea ;
Ribeiro, Helena Aguilar ;
Mendes, Adelio Magalhaes .
ENERGY & ENVIRONMENTAL SCIENCE, 2008, 1 (06) :655-667
[6]   Integrated dye-sensitized solar cell module with conversion efficiency of 8.2% [J].
Han, Liyuan ;
Fukui, Atsushi ;
Chiba, Yasuo ;
Islam, Ashraful ;
Komiya, Ryoichi ;
Fuke, Nobuhiro ;
Koide, Naoki ;
Yamanaka, Ryohsuke ;
Shimizu, Masafumi .
APPLIED PHYSICS LETTERS, 2009, 94 (01)
[7]   Improvement of efficiency of dye-sensitized solar cells by reduction of internal resistance [J].
Han, LY ;
Koide, N ;
Chiba, Y ;
Islam, A ;
Komiya, R ;
Fuke, N ;
Fukui, A ;
Yamanaka, R .
APPLIED PHYSICS LETTERS, 2005, 86 (21) :1-3
[8]   Modeling of an equivalent circuit for dye-sensitized solar cells [J].
Han, LY ;
Koide, N ;
Chiba, Y ;
Mitate, T .
APPLIED PHYSICS LETTERS, 2004, 84 (13) :2433-2435
[9]   Highly efficient photon-to-electron conversion of mercurochrome-sensitized nanoporous ZnO solar cells [J].
Hara, K ;
Horiguchi, T ;
Kinoshita, T ;
Sayama, K ;
Sugihara, H ;
Arakawa, H .
CHEMISTRY LETTERS, 2000, (04) :316-317
[10]   Long-term stability of organic-dye-sensitized solar cells based on an alkyl-functionalized carbazole dye [J].
Hara, Kohjiro ;
Wang, Zhong-Sheng ;
Cui, Yan ;
Furube, Akihiro ;
Koumura, Nagatoshi .
ENERGY & ENVIRONMENTAL SCIENCE, 2009, 2 (10) :1109-1114
123456