Mechanochemical reactions in alkali halide pressed disks

被引：30

作者：

FernandezBertran, J ^{[1
]}

Reguera, E ^{[1
]}

机构：

[1] UNIV HAVANA, IMRE, HAVANA 10400, CUBA

来源：

SOLID STATE IONICS | 1996年 / 93卷 / 1-2期

关键词：

mechanochemistry; infrared spectra; exchange reactions; oxidation-reduction reactions; solid solutions;

D O I：

10.1016/S0167-2738(96)00443-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mechanochemical reactions that take place when milling and pressing analytes with KBr to form a disk suitable for IR spectral work are reviewed. The topic is extended to other alkali halides matrices. The literature from 1952 is surveyed from an analytical point of view. Several reactions are discussed at length with emphasis on the nature of the products. The mechanism and the factors affecting the mechanochemical changes are discussed in detail for copper sulphate, alkaline and transition metal ferricyanides, and Ag, Hg and Pb salts.

引用

页码：139 / 146

页数：8

共 53 条

[1]

AMAKASU O, 1960, NIPPON KAGAKU ZASSHI, V81, P683

[2] SYNTHESIS AND PROPERTIES OF A SERIES OF PENTACYANOFERRATES [J].

AYERS, JB ;

WAGGONER, WH .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1969, 31 (07) :2045-&

[3] SYNTHESIS AND PROPERTIES OF 2 SERIES OF HEAVY METAL HEXACYANOFERRATES [J].

AYERS, JB ;

WAGGONER, WH .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1971, 33 (03) :721-&

[4] DIFFICULTIES AT THE INFRARED-SPECTROPHOTOMETRIC IDENTIFICATION AND ESTIMATION OF PURE COMPOUNDS AND MIXTURES BY USE OF POTASSIUM BROMIDE DISK TECHNIQUE [J].

BAK, B ;

CHRISTENSEN, D .

ACTA CHEMICA SCANDINAVICA, 1956, 10 (04) :692-694

[5] SOLID STATE ANOMALIES IN INFRARED SPECTROSCOPY [J].

BAKER, AW .

JOURNAL OF PHYSICAL CHEMISTRY, 1957, 61 (04) :450-458

[6]

BARKER SA, 1954, CHEM IND-LONDON, P1418

[7]

BENTEL E, 1929, MONATSH CHEM, V51, P369

[8] CHEMICAL-REACTIONS OF K3FE(CN)6 IN ALKALI-HALIDE DISKS [J].

BERTRAN, JF ;

PASCUAL, JB ;

HERNANDEZ, M .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1987, 43 (08) :981-981

[9] INFRA-RED SPECTRA OF INORGANIC SOLIDS .2. OXIDES, NITRIDES, CARBIDES, AND BORIDES [J].

BRAME, EG ;

MARGRAVE, JL ;

MELOCHE, VW .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1957, 5 (01) :48-52

[10] ZUR KENNTNIS DES IR-SPEKTRUMS OPTISCH AKTIVER AMINOSAUREN UND IHRER RACEMATE [J].

BROCKMANN, H ;

MUSSO, H .

CHEMISCHE BERICHTE-RECUEIL, 1956, 89 (02) :241-252

← 1 2 3 4 5 6 →