Molecular and crystal, structure of cadmium(II) diisobutyldithiocarbamate {Cd[(i-C4H9)2NCS2]2}2

被引：5

作者：

Glinskaya, LA ^{[1
]}

Zemskova, SM ^{[1
]}

Klevtsova, RF ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 1999年 / 40卷 / 06期

关键词：

Trigonal Bipyramid; Light Yellow Crystal; Tetragonal Pyramid; Clear Yellowish Solution; Equivalent Thermal Isotropic Parameter;

D O I：

10.1007/BF02700707

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Zinc(II) and cadmium(II) diethyldithiocarbamates (ML2) are promising volatile metal chelates having practical applications [I]. It is known that solid chelates ML2 are dimers in which the dithiocarbamate ions perform both cyclic bidentate and bridging cyclic tridentate functions. Here we report on the synthesis and molecular and crystal structure of the [Cd(i-Bu2NCS2)(2)](2) complex This study was undertaken to investigate the effect of the alkyl substituent on the character of crystal packing.

引用

页码：979 / 983

页数：5

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