Diels-Alder reactions of a 6-arenyl fulvene with dienes and dienophiles and related chemistry

被引：25

作者：

Nair, V ^{[1
]}

Anilkumar, G ^{[1
]}

Radhakrishnan, KV ^{[1
]}

Sheela, KC ^{[1
]}

Rath, NP ^{[1
]}

机构：

[1] UNIV MISSOURI,DEPT CHEM,ST LOUIS,MO 63121

来源：

TETRAHEDRON | 1997年 / 53卷 / 51期

关键词：

D O I：

10.1016/S0040-4020(97)10160-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

6-(2-Phenyl ethenyl) fulvene has been shown to participate both as diene and dienophile in Diels-Alder reactions and a facile photochemical transformation of the resulting bicyclo[2.2.2]-octenediones leading to extensively conjugated benzofulvenes has been accomplished. (C) 1997 Elsevier Science Ltd.

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收藏

页码：17361 / 17372

页数：12

相关论文

共 15 条

[1] GROUND-STATES OF MOLECULES .39. MNDO RESULTS FOR MOLECULES CONTAINING HYDROGEN, CARBON, NITROGEN, AND OXYGEN [J].

DEWAR, MJS ;

THIEL, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (15) :4907-4917

[2] GROUND-STATES OF MOLECULES .38. MNDO METHOD - APPROXIMATIONS AND PARAMETERS [J].

DEWAR, MJS ;

THIEL, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (15) :4899-4907

[3] SCOPE AND LIMITATIONS OF FULVENE SYNTHESES - PREPARATION OF 6-VINYL-SUBSTITUTED AND 6-VINYL-FUNCTIONALIZED FULVENES - FIRST EXAMPLES OF NUCLEOPHILIC-SUBSTITUTION ON A 6-(CHLOROMETHYL)FULVENE [J].

ERDEN, I ;

XU, FP ;

SADOUN, A ;

SMITH, W ;

SHEFF, G ;

OSSUN, M .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (04) :813-820

[4]

FRIEDRICHSEN W, 1978, LIEBIGS ANN CHEM, P440

[5]

GAJEWSKI JJ, 1971, TETRAHEDRON LETT, P1057

[6] SIMPLE SYNTHESIS OF 1,5-DIHYDROPENTALENES [J].

KAISER, R ;

HAFNER, K .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1973, 12 (04) :335-337

[7] [4 pi+2 pi]cycloaddition reactions of o-benzoquinones with symmetrical 6,6-dialkyl and cycloalkylfulvenes: Formation of bicyclo[2.2.2]octene diones and cyclopenta[b][1,4]benzodioxins. Some novel observations [J].

Nair, V ;

Kumar, S .

TETRAHEDRON, 1996, 52 (11) :4029-4040

[8] DIELS-ALDER REACTIONS OF O-BENZOQUINONES WITH 6-SUBSTITUTED FULVENES - FACILE SYNTHESIS OF 1-ARYL AND 1,1-DIARYLMETHYLENE-4,7-ETHANOINDENE-8,9-DIONES [J].

NAIR, V ;

KUMAR, S ;

ANILKUMAR, G ;

NAIR, JS .

TETRAHEDRON, 1995, 51 (33) :9155-9166

[9]

Nair V, 1997, SYNLETT, P767

[10]

Nair V, 1996, SYNLETT, P1143