Photoluminescent Polytellurophene Derivatives of Conjugated Polymers as a New Perspective for Molecular Electronics

被引:26
作者
Lapkowski, Mieczyslaw [1 ,2 ]
Motyka, Radoslaw [3 ]
Suwinski, Jerzy [3 ]
Data, Przemyslaw [1 ,2 ]
机构
[1] Silesian Tech Univ, Dept Phys Chem & Polymer Technol, PL-44100 Gliwice, Poland
[2] Polish Acad Sci, Ctr Polymer & Carbon Mat, PL-44100 Gliwice, Poland
[3] Silesian Tech Univ, Dept Organ Chem Bioorgan Chem & Biotechnol, PL-44100 Gliwice, Poland
关键词
conjugated polymers; molecular electronics; photoluminescence; polytellurophenes; LIGHT-EMITTING-DIODES; DONOR-ACCEPTOR HETEROJUNCTIONS; TRANSPORT; ELECTROPOLYMERIZATION; CELLS;
D O I
10.1002/macp.201100384
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The first full characterization of 2,2'-bitellurophene polymerization and the resulting polymer is described. The electrochemical polymerization of 2,2'-bitellurophene (7) and (E,E)-1,4-diethoxy-2,5-bis[2-(tellurophen-2-yl)ethenyl]benzene (1) produces new photoluminescent conjugated polymers. Poly{(E,E)-1,4-diethoxy-2,5-bis[2-(tellurophen-2-yl)ethenyl]benzene} exhibits photoluminescent properties that qualify for potential applications as optoelectronic materials. Poly{(E,E)-1,4-diethoxy-2,5-bis[2-(tellurophen-2-yl)ethenyl]benzene} is the first polytellurophene polymer that possess photoluminescent properties.
引用
收藏
页码:29 / 35
页数:7
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