The speed of sound, and derived thermodynamic properties of liquid trifluoromethane (HFC23) from T = (258 to 303) K at pressures up to 65 MPa

被引:10
作者
Pires, PF [1 ]
Guedes, HJR [1 ]
机构
[1] Univ Nova Lisboa, Fac Ciencias & Tecnol, Ctr Quim Fina & Biotecnol, Dept Quim, P-2825 Monte De Caparica, Portugal
关键词
speed of sound; alternative refrigerants; trifluoromethane; HFC23; thermodynamic properties;
D O I
10.1006/jcht.1998.0464
中图分类号
O414.1 [热力学];
学科分类号
摘要
This work reports experimental data of the speed of sound in liquid trifluoromethane (HFC23, or R23) from T = (258 to 303) K at pressures up to 65 MPa, measured with a pulse-echo method adapted from Papadakis((1)) and Guedes et al.((2)) The results are fitted to a rational approximant and compared with literature data.((3)) Derived thermodynamic properties such as the isentropic compressibility kappa(s), the isothermal compressibility kappa(T), the cubic expansion coefficient alpha(p), and the specific heat capacity at constant pressure c(p) are calculated by combining the present experimental data with the density values published by other authors.((4-11)) The estimated properties are compared, where possible, with literature data. (C) 1999 Academic Press.
引用
收藏
页码:479 / 490
页数:12
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