Properties of Glucosamide-Based Tetrasiloxane Surfactants

被引：9

作者：

Wang, Wanxu ^{[1
]}

Wang, Shujun ^{[1
]}

Du, Zhiping ^{[1
]}

Wang, Guoyong ^{[1
]}

Wang, Liang ^{[1
]}

机构：

[1] China Res Inst Daily Chem Ind, Taiyuan 030001, Shanxi Province, Peoples R China

来源：

JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY | 2012年 / 33卷 / 05期

关键词：

Glucosamide; spreading; surface tension; tetrasiloxane; MODIFIED CARBOHYDRATE SURFACTANTS; SPREADING MECHANISM; SILOXANYL MOIETIES; WETTING BEHAVIOR; TRISILOXANE; FAMILY; FILMS;

D O I：

10.1080/01932691.2011.579824

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

The interfacial properties of new glucosamide-based tetrasiloxane surfactants were studied. Members of the glucosamide-based tetrasiloxane surfactants reduce the surface tension of water to approximately 21 mN . m(-1) at concentration levels of 10(-5) mol . L-1. The wetting and spreading behavior of the glucosamide-based tetrasiloxane surfactants on Teflon and Paraffin were investigated and compared with that of trisiloxane. A new glucosamide-based tetrasiloxane beta shows the best spreading ability both on Teflon and Paraffin, which is similar with that of trisiloxane. It is suggested that a lower surface tension is a necessary but not sufficient condition for enhanced spreading. The spreading performance was affected by the hydrophilic-lipophilic balance (HLB) significantly. Furthermore, the molecular structure of the surfactant and the hydrophobic substrate also play important roles for showing spreading behavior.

引用

页码：654 / 659

页数：6

共 46 条

[1]

A STUDY OF THE SOLUTION, INTERFACIAL AND WETTING PROPERTIES OF SILICONE SURFACTANTS [J].

ANANTHAPADMANABHAN, KP ;

GODDARD, ED ;

CHANDAR, P .

COLLOIDS AND SURFACES, 1990, 44 :281-297

[2]

Surfactant-Enhanced Rapid Spreading of Drops on Solid Surfaces [J].

Beacham, D. R. ;

Matar, O. K. ;

Craster, R. V. .

LANGMUIR, 2009, 25 (24) :14174-14181

[3]

Synthesis of new cellobiose-based glycopolysiloxanes and their use as polymer stabilizers in miniemulsion polymerisation [J].

Berson, Solenn ;

Viet, D. ;

Halila, Sami ;

Driguez, Hugues ;

Fleury, Etienne ;

Hamaide, Thierry .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 2008, 209 (17) :1814-1825

[4]

Spreading of a water drop triggered by the surface tension gradient created by the localized addition of a surfactant [J].

Chengara, Anoop ;

Nikolov, Alex D. ;

Wasan, Darsh T. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2007, 46 (10) :2987-2995

[5]

Drew M., 1999, Surfaces, interfaces and colloids

[6]

Han F, 2004, ACTA CHIM SINICA, V62, P733

[7]

Han F, 2003, TENSIDE SURFACT DET, V40, P332

[8]

Han F., 2004, COLLOID SURFACE A, V237, P79

[9]

Han F., 2004, J SURFACTANTS DETERG, V7, P175

[10]

VOLUMETRIC BEHAVIOR OF MICELLIZATION OF ACYL-N-METHYLGLUCAMIDE SURFACTANTS IN WATER [J].

HARADA, S ;

SAHARA, H .

LANGMUIR, 1994, 10 (11) :4073-4076

← 1 2 3 4 5 →