Synthesis and characterization of a stable smaragdyrin isomer

被引：38

作者：

Sessler, JL ^{[1
]}

Davis, JM ^{[1
]}

Lynch, V ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Austin, TX 78741 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1998年 / 63卷 / 20期

关键词：

D O I：

10.1021/jo981019b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of 16,20-dipropyl-2,3,6,7,10,11,15,21-octamethyl-[22]pentaphyrin(1.1.1.0.0) (8), a stable isomer of smaragdyrin ([22]pentaphyrin(1.1.0.1.0)), and 9, a furan-containing analogue of 8, are reported. These two new expanded porphyrins were characterized in solution using UV-vis and H-1 and C-13 NMR spectroscopic means and in the solid state via single-crystal X-ray diffraction analysis.

引用

页码：7062 / 7065

页数：4

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