Ordered mesostructured carbon templated by SBA-16 silica

被引：24

作者：

Guo, WP ^{[1
]}

Su, FB ^{[1
]}

Zhao, XS ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 119260, Singapore

来源：

CARBON | 2005年 / 43卷 / 11期

关键词：

mesophase; carbonization; X-ray scattering; porosity;

D O I：

10.1016/j.carbon.2005.04.023

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel synthesis of ordered cubic mesoporous carbon with an Im3m symmetry by using SBA-16 silica as a hard template was performed. SBA-16 was synthesized using pluronic F 127 as the structure-directing agent and tetra- ethylorthosilicate as the silica source. Carbon replication of the surfactant-removed mesoporous silica was performed at 900°C using sucrose as a carbon source in the presence of sulfuric acid. It was found that surfactants removal method plays an important role in the formation of carbon mesostructures.

引用

页码：2423 / 2426

页数：4

共 23 条

[1] Cubic mesoporous silica with large controllable entrance sizes and advanced adsorption properties [J].

Fan, J ;

Yu, CZ ;

Gao, T ;

Lei, J ;

Tian, BZ ;

Wang, LM ;

Luo, Q ;

Tu, B ;

Zhou, WZ ;

Zhao, DY .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (27) :3146-3150

[2] Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles [J].

Joo, SH ;

Choi, SJ ;

Oh, I ;

Kwak, J ;

Liu, Z ;

Terasaki, O ;

Ryoo, R .

NATURE, 2001, 412 (6843) :169-172

[3] Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure [J].

Jun, S ;

Joo, SH ;

Ryoo, R ;

Kruk, M ;

Jaroniec, M ;

Liu, Z ;

Ohsuna, T ;

Terasaki, O .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (43) :10712-10713

[4] Structural study of mesoporous MCM-48 and carbon networks synthesized in the spaces of MCM-48 by electron crystallography [J].

Kaneda, M ;

Tsubakiyama, T ;

Carlsson, A ;

Sakamoto, Y ;

Ohsuna, T ;

Terasaki, O ;

Joo, SH ;

Ryoo, R .

JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (06) :1256-1266

[5] A low cost route to hexagonal mesostructured carbon molecular sieves [J].

Kim, SS ;

Pinnavaia, TJ .

CHEMICAL COMMUNICATIONS, 2001, (23) :2418-2419

[6] Determination and tailoring the pore entrance size in ordered silicas with cage-like mesoporous structures [J].

Kruk, M ;

Antochshuk, V ;

Matos, JR ;

Mercuri, LP ;

Jaroniec, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (05) :768-769

[7] Fabrication of novel mesocellular carbon foams with uniform ultralarge mesopores [J].

Lee, J ;

Sohn, K ;

Hyeon, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (21) :5146-5147

[8]

Lee J, 2000, ADV MATER, V12, P359, DOI 10.1002/(SICI)1521-4095(200003)12:5<359::AID-ADMA359>3.0.CO

[9]

2-1

[10] Synthesis of a new mesoporous carbon and its application to electrochemical double-layer capacitors [J].

Lee, J ;

Yoon, S ;

Hyeon, T ;

Oh, SM ;

Kim, KB .

CHEMICAL COMMUNICATIONS, 1999, (21) :2177-2178

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