Blue-to-green electrophosphorescence of iridium-based cyclometallated materials

被引：103

作者：

Mak, CSK

Hayer, A

Pascu, SI

Watkins, SE

Holmes, AB

Köhler, A

Friend, RH

机构：

[1] Univ Cambridge, Dept Chem, Melville Lab Polymer Synth, Cambridge CB2 1EW, England

[2] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia

[3] Univ Melbourne, Inst Bio21, Melbourne, Vic 3010, Australia

[4] Univ Cambridge, Cavendish Lab, Dept Phys, Cambridge CB3 0HE, England

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 37期

关键词：

D O I：

10.1039/b508695g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photo- and electroluminescence properties of a series of novel, heteroleptic, mer-cyclometallated iridium complexes have been fine-tuned from green to blue by changing the substituents on the pyridyl ring of the phenylpyridyl ligand. The X-ray crystal structures of two Ir-based triazolyl complexes are reported.

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页码：4708 / 4710

页数：3

相关论文

共 24 条

[1] Endothermic energy transfer: A mechanism for generating very efficient high-energy phosphorescent emission in organic materials [J].

Adachi, C ;

Kwong, RC ;

Djurovich, P ;

Adamovich, V ;

Baldo, MA ;

Thompson, ME ;

Forrest, SR .

APPLIED PHYSICS LETTERS, 2001, 79 (13) :2082-2084

[2] Very high-efficiency green organic light-emitting devices based on electrophosphorescence [J].

Baldo, MA ;

Lamansky, S ;

Burrows, PE ;

Thompson, ME ;

Forrest, SR .

APPLIED PHYSICS LETTERS, 1999, 75 (01) :4-6

[3] Highly efficient phosphorescent emission from organic electroluminescent devices [J].

Baldo, MA ;

O'Brien, DF ;

You, Y ;

Shoustikov, A ;

Sibley, S ;

Thompson, ME ;

Forrest, SR .

NATURE, 1998, 395 (6698) :151-154

[4] Synthesis and characterization of phosphorescent cyclometalated platinum complexes [J].

Brooks, J ;

Babayan, Y ;

Lamansky, S ;

Djurovich, PI ;

Tsyba, I ;

Bau, R ;

Thompson, ME .

INORGANIC CHEMISTRY, 2002, 41 (12) :3055-3066

[5] High-efficiency red-light emission from polyfluorenes grafted with cyclometalated iridium complexes and charge transport moiety [J].

Chen, XW ;

Liao, JL ;

Liang, YM ;

Ahmed, MO ;

Tseng, HE ;

Chen, SA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (03) :636-637

[6] Tuning iridium(III) phenylpyridine complexes in the "almost blue" region [J].

Coppo, P ;

Plummer, EA ;

De Cola, L .

CHEMICAL COMMUNICATIONS, 2004, (15) :1774-1775

[7]

Gong X, 2003, ADV MATER, V15, P45, DOI 10.1002/adma.200390007

[8]

Gong X, 2002, ADV MATER, V14, P581, DOI 10.1002/1521-4095(20020418)14:8<581::AID-ADMA581>3.0.CO

[9]

2-B

[10] Phosphorescence from iridium complexes doped into polymer blends [J].

Gong, X ;

Lim, SH ;

Ostrowski, JC ;

Moses, D ;

Bardeen, CJ ;

Bazan, GC .

JOURNAL OF APPLIED PHYSICS, 2004, 95 (03) :948-953