Influence of distributed secondary gas injection on the performance of a bubbling fluidized-bed reactor

被引:35
作者
Christensen, D. [1 ]
Nijenhuis, J. [1 ]
van Ommen, J. R. [1 ]
Coppens, M. -O. [1 ,2 ]
机构
[1] Delft Univ Technol, Delft, Netherlands
[2] Rensselaer Polytech Inst, Dept Chem & Biochem Engn, Troy, NY 12180 USA
关键词
D O I
10.1021/ie071376p
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Distributed secondary gas injection via a fractal injector was studied in a lab-scale 3-D fluidized bed to determine its effect on bubble size, bubble fraction, residence time, mixing, and conversion. The experimental results indicate improved reactor performance and are consistent with earlier work in 2-D beds. A model was developed based on simple two-phase theory that describes the effect of distributed secondary injection on the performance of ozone decomposition in a bubbling fluidized bed. The model was used to predict the performance of a reactor for the production of maleic anhydride from n-butane, which includes consecutive and side reactions. The results showed that the production and selectivity of maleic anhydride were significantly improved. It can be concluded that distributed secondary gas injection improves the mass transfer and gassolid contact, which results in increased reactor performance. It likely achieves these improvements by enhanced gas flow through the dense phase and more micromixing around the injection points, which causes greater interaction between the phases. Some aspects of applying this technology in industry are discussed.
引用
收藏
页码:3601 / 3618
页数:18
相关论文
共 29 条
[1]   BEHAVIOR OF GAS-FLUIDIZED BEDS OF FINE POWDERS .2. VOIDAGE OF THE DENSE PHASE IN BUBBLING BEDS [J].
ABRAHAMSEN, AR ;
GELDART, D .
POWDER TECHNOLOGY, 1980, 26 (01) :47-55
[2]   RESIDENCE-TIME DISTRIBUTIONS FOR SYSTEMS HAVING MANY CONNECTIONS WITH THEIR ENVIRONMENTS [J].
BUFFHAM, BA ;
KROPHOLLER, HW .
INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1981, 20 (01) :102-104
[3]   NORMAL-BUTANE OXIDATION TO MALEIC-ANHYDRIDE ON VANADIUM PHOSPHORUS OXIDES - KINETIC-ANALYSIS WITH A TUBULAR FLOW STACKED-PELLET REACTOR [J].
CENTI, G ;
FORNASARI, G ;
TRIFIRO, F .
INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1985, 24 (01) :32-37
[4]  
Chen N. H., 1962, J CHEM ENG DATA, V7, P37, DOI DOI 10.1021/JE60012A011
[5]  
CHEN NH, 1962, J CHEM ENG DATA, V7, P306
[6]   A model for the interpretation of the bed collapse experiment [J].
Cherntongchai, P ;
Brandani, S .
POWDER TECHNOLOGY, 2005, 151 (1-3) :37-43
[7]   Residence times in fluidized beds with secondary gas injection [J].
Christensen, D. ;
Nijenhuis, J. ;
Van Ornmen, J. R. ;
Coppens, M. -O. .
POWDER TECHNOLOGY, 2008, 180 (03) :321-331
[8]  
CHRISTENSEN D, 2007, ECI S SERIES RP, V4
[9]  
CHRISTENSEN D, 2008, POWDER TECHNOL, DOI DOI 10.1016/J.P0WTEC.2008.01.021
[10]  
DARTON RC, 1977, T I CHEM ENG-LOND, V55, P274