Recent catalytic advances in the chemistry of substituted furans from carbohydrates and in the ensuing polymers

被引:484
作者
Moreau, C
Belgacem, MN
Gandini, A
机构
[1] Ecole Natl Super Chim Montpellier, Lab Mat Catalyt & Catalyse Chim Organ, CNRS, UMR 5618, F-34296 Montpellier 5, France
[2] Inst Natl Polytech Grenoble, Ecole Francaise Papeterie & Ind Graph, CTP, Lab Genie Procedes Papetiers,CNRS,UMR 5518, F-38402 St Martin Dheres, France
关键词
carbohydrates; catalysis; furanic monomers; furanic polymers;
D O I
10.1023/B:TOCA.0000013537.13540.0e
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this review, an overview is given on the last development of catalytic methods for the preparation of substituted furans from carbohydrates and ensuing polymers. The review starts with the recent aspects in the synthesis of some key furan monomers in the presence of solid catalysts. In the second part, selected examples are given of polymerization systems leading to furan-based materials with promising properties, thus constituting a serious alternative to petroleum-based counterparts. Finally, a short examination is given on what could be the future of furan chemistry with the recent development of ionic liquids as solvents.
引用
收藏
页码:11 / 30
页数:20
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