Switching enantiofacial selectivities using one chiral source:: Catalytic enantioselective synthesis of the key intermediate for (20S)-camptothecin family by (S)-selective cyanosilylation of ketones

被引：228

作者：

Yabu, K

Masumoto, S

Yamasaki, S

Hamashima, Y

Kanai, M

Du, W

Curran, DP

Shibasaki, M ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Pharmaceut Sci, Bunkyo Ku, Tokyo 1130033, Japan

[2] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2001年 / 123卷 / 40期

关键词：

D O I：

10.1021/ja016682n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

收藏

页码：9908 / 9909

页数：2

相关论文

共 13 条

[1] Optimized catalysts for the asymmetric addition of trimethylsilyl cyanide to aldehydes and ketones
Belokon, YN
Green, B
Ikonnikov, NS
North, M
Parsons, T
Tararov, VI
[J]. TETRAHEDRON, 2001, 57 (04) : 771 - 779
[2] Corey EJ, 1998, ANGEW CHEM INT EDIT, V37, P388, DOI 10.1002/(SICI)1521-3773(19980302)37:4<388::AID-ANIE388>3.0.CO
[3] 2-V
[4] Cyanohydrins in nature and the laboratory: Biology, preparations, and synthetic applications
Gregory, RJH
[J]. CHEMICAL REVIEWS, 1999, 99 (12) : 3649 - 3682
[5] Catalytic enantioselective cyanosilylation of ketones: improvement of enantioselectivity and catalyst turn-over by ligand tuning
Hamashima, Y
Kanai, M
Shibasaki, M
[J]. TETRAHEDRON LETTERS, 2001, 42 (04) : 691 - 694
[6] Catalytic enantioselective cyanosilylation of ketones
Hamashima, Y
Kanai, M
Shibasaki, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (30) : 7412 - 7413
[7] HOVEYDA AH, 2000, STIMULATING CONCEPTS, P145
[8] Josien H, 1998, CHEM-EUR J, V4, P67, DOI 10.1002/(SICI)1521-3765(199801)4:1<67::AID-CHEM67>3.0.CO
[9] 2-F
[10] Lanthanide trifluoromethanesulfonate-catalyzed asymmetric aldol reactions in aqueous media
Kobayashi, S
Hamada, T
Nagayama, S
Manabe, K
[J]. ORGANIC LETTERS, 2001, 3 (02) : 165 - 167