Mechanistic inferences derived from competitive catalytic reactions: Pd(binap)-catalyzed amination of aryl halides

被引：17

作者：

Ferretti, Antonio C. ^{[1
]}

Mathew, Jinu S. ^{[2
]}

Ashworth, Ian ^{[3
]}

Purdy, Malcolm ^{[3
]}

Brennan, Colin ^{[3
]}

Blackmond, Donna G. ^{[1
,2
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem Engn & Chem Technol, London SW7 2AZ, England

[2] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

[3] Syngenta, Proc Studies Grp, Huddersfield HD2 1FF, W Yorkshire, England

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2008年 / 350卷 / 7-8期

关键词：

amination; aryl halides; kinetic resolution; kinetics;

D O I：

10.1002/adsc.200800006

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The Pd(binap)-catalyzed amination of aryl halides demonstrates how the results from competitive reactions can be strikingly different from those obtained from study of the separate reactions. We show how the competitive network provides mechanistic information not accessible from study of the reactions separately.

引用

页码：1007 / 1012

页数：6

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