[Cu(dap)2Cl] As an Efficient Visible-Light-Driven Photoredox Catalyst in Carbon-Carbon Bond-Forming Reactions

被引：275

作者：

Pirtsch, Michael ^{[1
]}

Paria, Suva ^{[1
]}

Matsuno, Taisuke ^{[1
,2
]}

Isobe, Hiroyuki ^{[2
]}

Reiser, Oliver ^{[1
]}

机构：

[1] Univ Regensburg, Inst Organ Chem, D-93053 Regensburg, Germany

[2] Tohoku Univ, Dept Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 24期

关键词：

allylation; atom-transfer radical addition; copper; photochemistry; redox chemistry; ELECTRON-TRANSFER; RADICAL-ADDITION; ATOM-TRANSFER; PHOTOCATALYSIS; KETONES; 1-BENZYL-1,4-DIHYDRONICOTINAMIDE; PHOTOCHEMISTRY; CYCLIZATION; GENERATION; REDUCTION;

D O I：

10.1002/chem.201200967

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper sees the light of day: [Cu(dap) 2Cl] proved to be an excellent photoredox catalyst for atom-transfer radical addition reactions, as well as for allylation reactions (see scheme), providing an attractive alternative to commonly used iridium- and ruthenium-based catalysts. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7336 / 7340

页数：5

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