Phase transformation induced in pure zirconia by high energy heavy ion irradiation

Samples of monoclinic zirconia were irradiated with heavy ions having incident energies in the range of a few hundred MeV giving then rise to a slowing down essentially caused by high electronic excitations. The characterizations of the samples by X-ray diffraction and complementary Raman spectroscopy analyses revealed two main features. First, in the electronic stopping power regime, it is only when the electronic energy loss is above a threshold near 13 keV nm(-1) that monoclinic zirconia undergoes a transformation to the tetragonal phase. Second, the evolution of the amount of the tetragonal phase with the ion fluence exhibits a sigmoidal shape suggesting a mechanism for phase transformation which very likely needs two ion impacts. (C) 2001 Elsevier Science B.V. All rights reserved.