Specific interactions between aromatic electrons of organic compounds and graphite surfaces as detected by immersion calorimetry

被引：21

作者：

Castillejos-Lopéz, E

Nevskaia, DM

Muñoz, V

Rodríiguez-Ramos, I

Guerrero-Ruiz, A

机构：

[1] Univ Nacl Educ Distancia, Fac Ciencias, Dpto Quim Inorgan & Quim Tecn, Madrid 28040, Spain

[2] CSIC, Inst Catalisis & Petrol, E-28049 Madrid, Spain

来源：

LANGMUIR | 2004年 / 20卷 / 04期

关键词：

D O I：

10.1021/la035349p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The interaction of toluene and methylcyclohexane with the surface of a series of graphites differing in surface area has been studied by immersion calorimetry. Comparison of the immersion enthalpies that evolved when the solids were immersed into the distinct liquids reveals the formation of charge-transfer complexes among aromatic electrons of the organic molecules and the edges and lateral faces of the graphite surface.

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页码：1013 / 1015

页数：3

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