A Diagonal Approach to Chemical Recycling of Carbon Dioxide: Organocatalytic Transformation for the Reductive Functionalization of CO2

被引：442

作者：

Gomes, Christophe Das Neves ^{[1
]}

Jacquet, Olivier ^{[1
]}

Villiers, Claude ^{[1
]}

Thuery, Pierre ^{[1
]}

Ephritikhine, Michel ^{[1
]}

Cantat, Thibault ^{[1
]}

机构：

[1] CEA, IRAMIS, CNRS UMR 3299, SIS2M, F-91191 Gif Sur Yvette, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 01期

关键词：

carbon dioxide; density functional calculations; organocatalysis; reduction; silanes; ROOM-TEMPERATURE; COMPLEXES; HYDROGENATION; CARBOXYLATION; CATALYSTS; HYDROSILANES; CONVERSION; ALKYNES;

D O I：

10.1002/anie.201105516

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lateral thinking: A diagonal approach to CO 2 recycling has been explored for the formation of both functionalized and energetic chemicals featuring a reduced carbon center. The strategy relies on the tandem use of a functionalization reagent and a reductant that can be independently modified to access a wide spectrum of chemicals from CO 2. It is exemplified with an organocatalytic process to convert CO 2 into formamides (see picture). © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：187 / 190

页数：4

共 32 条

[1]

[Anonymous], 2007, TRACKING IND ENERGY

[2]

[Anonymous], 2010, ANGEW CHE, DOI DOI 10.1002/ANGE.201004263

[3]

[Anonymous], 2011, ANGEW CHEM-GER EDIT

[4]

Aresta M., 2010, CARBON DIOXIDE CHEM

[5] Electrocatalytic and homogeneous approaches to conversion of CO2 to liquid fuels [J].

Benson, Eric E. ;

Kubiak, Clifford P. ;

Sathrum, Aaron J. ;

Smieja, Jonathan M. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (01) :89-99

[6] Tandem Frustrated Lewis Pair/Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide [J].

Berkefeld, Andreas ;

Piers, Warren E. ;

Parvez, Masood .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (31) :10660-10661

[7] Carboxylation of C-H Bonds Using N-Heterocyclic Carbene Gold(I) Complexes [J].

Boogaerts, Ine I. F. ;

Nolan, Steven P. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (26) :8858-+

[8] Palladium-Catalyzed Direct Carboxylation of Aryl Bromides with Carbon Dioxide [J].

Correa, Arkaitz ;

Martin, Ruben .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (44) :15974-+

[9] Making plastics from carbon dioxide:: Salen metal complexes as catalysts for the production of polycarbonates from epoxides and CO2 [J].

Darensbourg, Donald J. .

CHEMICAL REVIEWS, 2007, 107 (06) :2388-2410

[10] Converting carbon dioxide into carbamato derivatives [J].

Dell'Amico, DB ;

Calderazzo, F ;

Labella, L ;

Marchetti, F ;

Pampaloni, G .

CHEMICAL REVIEWS, 2003, 103 (10) :3857-3897

← 1 2 3 4 →