Lithium Intercalation Studies on MoO3 Single Crystals

被引：5

作者：

Hatzikraniotis, E. ^{[1
]}

Samaras, I. ^{[1
]}

Paraskevopoulos, K. M. ^{[1
]}

Julien, C. ^{[2
]}

机构：

[1] Univ Thessaloniki, Dept Solid State Phys, GR-54006 Thessaloniki, Greece

[2] Univ Paris 06, Phys Solides Lab, Paris, France

来源：

IONICS | 1996年 / 2卷 / 01期

关键词：

D O I：

10.1007/BF02375864

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The intercalation process of Li in molybdenum trioxide (MoO3), a layered transition metal oxide that has been proposed as candidate cathode material for rechargeable batteries, is examined in relation to the crystallinity and the growth method of the pristine material. Atomic Force Microscopy (AFM) is used for surface roughness calculations. Roughness is enhanced with intercalation at the early stages and as the process proceeds, randomly scattered domains merge into ordered clusters, and finally a fragmented surface is formed.

引用

页码：24 / 28

页数：5

共 11 条

[1]

AGNIHOTRY SA, 1986, INDIAN J PURE AP PHY, V24, P19

[2] PHYSICAL PROPERTIES OF A TRANSITION METAL OXIDE - OPTICAL AND PHOTOELECTRIC PROPERTIES OF SINGLE CRYSTAL AND THIN FILM MOLYBDENUM TRIOXIDE [J].

DEB, SK .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1968, 304 (1477) :211-&

[3]

FAUGHNAN BW, 1980, TOP APPL PHYS, V40, P181

[4] ELECTROCHEMICAL STUDIES OF LITHIUM INSERTION IN MOO3 FILMS [J].

JULIEN, C ;

HUSSAIN, OM ;

ELFARH, L ;

BALKANSKI, M .

SOLID STATE IONICS, 1992, 53 (pt 1) :400-404

[5] PREPARATION AND ELECTROCHROMIC PROPERTIES OF RF-SPUTTERED MOLYBDENUM OXIDE-FILMS [J].

MIYATA, N ;

AKIYOSHI, S .

JOURNAL OF APPLIED PHYSICS, 1985, 58 (04) :1651-1655

[6] FAR-INFRARED AND RAMAN STUDIES OF ORTHORHOMBIC MOO3 SINGLE-CRYSTAL [J].

NAZRI, GA ;

JULIEN, C .

SOLID STATE IONICS, 1992, 53 (pt 1) :376-382

[7]

STERGIOU A, UNPUB

[8]

SVENSSON JSEM, 1984, P SOC PHOTO-OPT INST, V502, P30, DOI 10.1117/12.944782

[9] CHEMISTRY OF INTERCALATION COMPOUNDS - METAL GUESTS IN CHALCOGENIDE HOSTS [J].

WHITTINGHAM, MS .

PROGRESS IN SOLID STATE CHEMISTRY, 1978, 12 (01) :41-99

[10] SOME ANOMALOUS OPTICAL AND ELECTRICAL-PROPERTIES OF THE M/MOO3/M SANDWICH STRUCTURE [J].

YUAN, YF ;

HEAVENS, OS .

THIN SOLID FILMS, 1992, 217 (1-2) :138-145

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