Solid-state self-assembly of a complex from 1,3,5-benzenetricarboxylic acid and 1,3,5-trihydroxybenzene:: influence of strong O-H•••O and C-H•••O hydrogen bonds

被引：40

作者：

Liu, R ^{[1
]}

Mok, KF ^{[1
]}

Valiyaveettil, S ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

来源：

NEW JOURNAL OF CHEMISTRY | 2001年 / 25卷 / 07期

关键词：

D O I：

10.1039/b102098f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1,3,5-Benzenetricarboxylic acid (trimesic acid, TMA) was cocrystallized with 0.5 equiv. of 1,3,5-trihydroxybenzene (phloroglucinol, THB) to generate a close-packed non-interpenetrating planar mosaic motif. Both O-H . . .O and C-H . . .O hydrogen bonds were observed in the crystal lattice. Each THB molecule is hydrogen bonded to six adjacent TMA molecules to form a planar rosette-shaped structure, which constitutes the repeating units of a layer-type lattice.

引用

页码：890 / 892

页数：3

共 14 条

[1] SUPRAMOLECULAR SYNTHONS IN CRYSTAL ENGINEERING - A NEW ORGANIC-SYNTHESIS [J].

DESIRAJU, GR .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (21) :2311-2327

[2] Dynamic aspects of lattice inclusion complexation involving a phase change. Equilibrium, kinetics, and energetics of guest-binding to a hydrogen-bonded flexible organic network [J].

Dewa, T ;

Endo, K ;

Aoyama, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (35) :8933-8940

[3] CRYSTAL STRUCTURE OF TRIMESIC ACID (BENZENE-1,3,5-TRICARBOXYLIC ACID) [J].

DUCHAMP, DJ ;

MARSH, RE .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1969, B 25 :5-&

[4] Functional self-assembly of hydrogen-bonded networks. Construction of aromatic stacks and columns and cavity-size control via flexible intercalation of 1D chains having orthogonal aromatic substituents [J].

Endo, K ;

Ezuhara, T ;

Koyanagi, M ;

Masuda, H ;

Aoyama, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (03) :499-505

[5]

HERBSTEIN FH, 1987, TOP CURR CHEM, V140, P107

[6] CATENATED AND NON-CATENATED INCLUSION COMPLEXES OF TRIMESIC ACID [J].

HERBSTEIN, FH ;

KAPON, M ;

REISNER, GM .

JOURNAL OF INCLUSION PHENOMENA, 1987, 5 (02) :211-214

[7]

HERBSTEIN JL, 1996, COMPREHENSIVE SUPRAM, V6, pCH3

[8] Crystal engineering: molecular networks based on inclusion phenomena [J].

Hosseini, MW ;

De Cian, A .

CHEMICAL COMMUNICATIONS, 1998, (07) :727-733

[9]

Kolotuchin SV, 1999, CHEM-EUR J, V5, P2537, DOI 10.1002/(SICI)1521-3765(19990903)5:9<2537::AID-CHEM2537>3.0.CO

[10]

2-3

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