Snowflake-like dendrimers via site-selective synthesis of dendrons

被引:43
作者
Kozaki, M [1 ]
Okada, K [1 ]
机构
[1] Osaka City Univ, Grad Sch Sci, Sumiyoshi Ku, Osaka 5588585, Japan
关键词
D O I
10.1021/ol036011p
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Snowflake-shaped dendrimers were prepared via site-selective synthesis of dendrons, where an attachment of encapsulating dendritic branches and an extension of phenylacetylenic units were alternatively manipulated on the structure of AB(2) (diethyltriazeno for A and bromo for B) substituted diphenylacetylene using a combination of Suzuki and Sonogashira cross-coupling reactions.
引用
收藏
页码:485 / 488
页数:4
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