General and Controllable Synthesis of Novel Mesoporous Magnetic Iron Oxide@Carbon Encapsulates for Efficient Arsenic Removal

被引:321
作者
Wu, Zhangxiong [1 ,2 ,3 ]
Li, Wei [2 ,3 ]
Webley, Paul A. [1 ]
Zhao, Dongyuan [1 ,2 ,3 ]
机构
[1] Monash Univ, Fac Engn, Dept Chem Engn, Melbourne, Vic 3800, Australia
[2] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[3] Fudan Univ, Adv Mat Lab, Shanghai 200433, Peoples R China
基金
澳大利亚研究理事会;
关键词
mesoporous carbon; metal oxide nanoparticles; confined synthesis; arsenic removal; HIGH SURFACE-AREAS; COUPLING REACTION; ADSORPTION; NANOPARTICLES; FUNCTIONALIZATION; WATER; TRANSFORMATION; ARCHITECTURE; PERFORMANCE; COMPOSITES;
D O I
10.1002/adma.201103789
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A facile ammonia-atmosphere prehydrolysis post-synthetic route that can uniformly and selectively deposit Fe(2)O(3) nanoparticles in the predefined mesopores (5.6 nm) of a bimodal (2.3, 5.6 nm) mesoporous carbon matrix is demonstrated (see figure). The mesoporous magnetic Fe(2)O(3)@C encapsulates show excellent performance for arsenic capture with remarkable adsorption capacity, fast uptake rate, easy magnetic separation, and good cyclic stability.
引用
收藏
页码:485 / +
页数:8
相关论文
共 40 条
[1]   Water-Dispersible Magnetite-Reduced Graphene Oxide Composites for Arsenic Removal [J].
Chandra, Vimlesh ;
Park, Jaesung ;
Chun, Young ;
Lee, Jung Woo ;
Hwang, In-Chul ;
Kim, Kwang S. .
ACS NANO, 2010, 4 (07) :3979-3986
[2]   Arsenic removal by iron-modified activated carbon [J].
Chen, Weifang ;
Parette, Robert ;
Zou, Jiying ;
Cannon, Fred S. ;
Dempsey, Brian A. .
WATER RESEARCH, 2007, 41 (09) :1851-1858
[3]   Gold Nanoparticles Embedded in a Mesoporous Carbon Nitride Stabilizer for Highly Efficient Three-Component Coupling Reaction [J].
Datta, K. K. R. ;
Reddy, B. V. Subba ;
Ariga, Katsuhiko ;
Vinu, Ajayan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (34) :5961-5965
[4]   Arsenic removal using a polymeric/inorganic hybrid sorbent [J].
DeMarco, MJ ;
Sengupta, AK ;
Greenleaf, JE .
WATER RESEARCH, 2003, 37 (01) :164-176
[5]   Controlled Synthesis and Functionalization of Ordered Large-Pore Mesoporous Carbons [J].
Deng, Yonghui ;
Cai, Yue ;
Sun, Zhenkun ;
Gu, Dong ;
Wei, Jing ;
Li, Wei ;
Guo, Xiaohui ;
Yang, Jianping ;
Zhao, Dongyuan .
ADVANCED FUNCTIONAL MATERIALS, 2010, 20 (21) :3658-3665
[6]   Synthesis and magnetic properties of mesostructured γ-Fe2O3/carbon composites by a Co-casting method [J].
Dong, Xiaoping ;
Chen, Hangrong ;
Zhao, Wenru ;
Li, Xia ;
Shi, Jianlin .
CHEMISTRY OF MATERIALS, 2007, 19 (14) :3484-3490
[7]   Synthesis and evaluation of iron-containing ordered mesoporous carbon (FeOMC) for arsenic adsorption [J].
Gu, Zhimang ;
Deng, Baolin ;
Yang, John .
MICROPOROUS AND MESOPOROUS MATERIALS, 2007, 102 (1-3) :265-273
[8]   Preparation and evaluation of GAC-based iron-containing adsorbents for arsenic removal [J].
Gu, ZM ;
Fang, J ;
Deng, BL .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2005, 39 (10) :3833-3843
[9]   Removal of arsenic by bead cellulose loaded with iron oxyhydroxide from groundwater [J].
Guo, XJ ;
Chen, FH .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2005, 39 (17) :6808-6818
[10]   Arsenic removal from drinking water during coagulation [J].
Hering, JG ;
Chen, PY ;
Wilkie, JA ;
Elimelech, M .
JOURNAL OF ENVIRONMENTAL ENGINEERING-ASCE, 1997, 123 (08) :800-807