Non-metathesis ruthenium-catalyzed C-C bond formation

被引：776

作者：

Trost, BM ^{[1
]}

Toste, FD ^{[1
]}

Pinkerton, AB ^{[1
]}

机构：

[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA

来源：

CHEMICAL REVIEWS | 2001年 / 101卷 / 07期

关键词：

D O I：

10.1021/cr000666b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The non-metathesis ruthenium-catalyzed C-C bond formation was discussed. The reactions involving heteroatom additions to alkynes and allyl-ruthenium intermediates were elaborated. The oxa-ene reaction of electron-deficient aldehydes and alkenes was found to be catalyzed using cationic ruthenium-salen complex in nitromethane at 50°C. The cross-coupling of vinyl halides with olefins and alkyl Grignard reagents catalyzed by ruthenium complexes was also elaborated.

引用

页码：2067 / 2096

页数：30

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