Platinum(II) and palladium(II) saccharinate complexes

被引：50

作者：

Henderson, W ^{[1
]}

Nicholson, BK ^{[1
]}

McCaffrey, LJ ^{[1
]}

机构：

[1] Univ Waikato, Dept Chem, Hamilton, New Zealand

来源：

INORGANICA CHIMICA ACTA | 1999年 / 285卷 / 01期

关键词：

crystal structures; platinum complexes; palladium complexes; saccharin complexes;

D O I：

10.1016/S0020-1693(98)00327-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A number of platinum(II) and palladium(II) complexes containing the saccharinate ligand (sac(-)), of the type [MCl(sac)L-2](M = Pt, L = PPh3, L-2 = Ph2PCH2CH2PPh2, dppe; M = Pd, L = PPh3) have been synthesised by reaction of [MCl2L2] with sacNa in methanol. A single crystal X-ray diffraction study carried out on cis-[PtCl(sac)(PPh3)(2)]. 4CHCl(3) shows the N-bonded saccharinate and platinum coordination planes to be nearly orthogonal. The results of an electrospray mass spectrometric study of the dppe complex are also reported. (C) 1999 Elsevier Science S.A. All rights reserved.

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页码：145 / 148

页数：4

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