Two genuine supramolecular isomers exhibiting hierarchical resemblance and distinction

被引：20

作者：

Peng, Rong ^{[1
]}

Li, Mian ^{[1
]}

Deng, Shi-Ren ^{[2
]}

Li, Zao-Ying ^{[2
]}

Li, Dan ^{[1
]}

机构：

[1] Shantou Univ, Dept Chem, Shantou 515063, Guangdong, Peoples R China

[2] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China

来源：

CRYSTENGCOMM | 2010年 / 12卷 / 11期

基金：

中国国家自然科学基金;

关键词：

FLEXIBLE THIOETHER LIGAND; COORDINATION POLYMERS; METAL-COMPLEXES; NETS; POLYMORPHS; CHEMISTRY; CONCOMITANT; SOLIDS;

D O I：

10.1039/c0ce00163e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two supramolecular isomers based on CuCN and 3,4-bis(4-pyridinesulfanylmethyl)thiophene exhibited conformational, topological, catenane and optical isomerism within tectonic, molecular and supramolecular levels, respectively. At the material level, the two isomeric compounds displayed diverse photoluminescence, emitting at 517 nm and 553 nm, respectively, in the solid state at room temperature.

引用

页码：3670 / 3675

页数：6

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