A photoreactive crystalline quasiracemate

被引：41

作者：

Grove, Rebecca C. ^{[1
]}

Malehorn, Steven H. ^{[1
]}

Breen, Meghan E. ^{[1
]}

Wheeler, Kraig A. ^{[1
]}

机构：

[1] Eastern Illinois Univ, Dept Chem, Charleston, IL 61920 USA

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 39期

基金：

美国国家科学基金会;

关键词：

SOLID-STATE REACTIONS; SINGLE-CRYSTAL; PHOTOCHEMICAL-REACTIONS; 2+2 CYCLOADDITION; CHIRAL CRYSTALS; PHOTODIMERIZATION; ACIDS; HOST; PHOTOPOLYMERIZATION; TOPOCHEMISTRY;

D O I：

10.1039/c0cc02775h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rationally designed racemic and quasiracemic sulfonamidecinnamic acids assemble to give hydrogen-bonded dimers with coplanar alignment of neighboring olefins. The quasiracemate phase contains near inversion-related motifs with chemically distinct components forming supramolecular heterodimers that undergo asymmetric photodimerization.

引用

页码：7322 / 7324

页数：3

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