A bivanadyl capped, highly reduced Keggin polyanion, [PMo(V)(6)Mo(VI)(6)O(40)(V(IV)O)(2)](5-)

被引：154

作者：

Chen, Q ^{[1
]}

Hill, CL ^{[1
]}

机构：

[1] EMORY UNIV,DEPT CHEM,ATLANTA,GA 30322

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 08期

关键词：

D O I：

10.1021/ic951231n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A bicapped, highly reduced vanadylpolymolybdophosphate Keggin complex [(C2H5)(3)NH](5)[(PMo6Mo6O40)-Mo-V-O-VI-((VO)-O-IV)(2)], (TEA) 1, has been prepared hydrothermally and characterized by single-crystal X-ray diffraction, LR, UV/visible, cyclic voltammetry, elemental analysis, redox titration, and V-51 and P-31 NMR on its degradation products. The kinetics of decomposition of 1 in aqueous solution under both aerobic and anaerobic conditions is complex.

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页码：2403 / &

页数：4

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