CO2 reforming of methane on Rh/Al2O3 catalyst

被引：48

作者：

Nagai, Masatoshi

Nakahira, Keita

Ozawa, Yasushi

Namiki, Yoshika

Suzuki, Youji

机构：

[1] Tokyo Univ Agr & Technol, Grad Sch Bioapplicat & Syst Engn, Koganei, Tokyo 1848588, Japan

[2] Cent Res Inst Elect Power Ind, Energy Engn Res Lab, Yokosuka, Kanagawa 2400196, Japan

[3] Nihon Univ, Fac Engn, Dept Ind Chem, Chiba 275, Japan

来源：

CHEMICAL ENGINEERING SCIENCE | 2007年 / 62卷 / 18-20期

关键词：

catalysis; catalyst selectivity; catalyst support; fuel; methane; reforming; CO2; Rh;

D O I：

10.1016/j.ces.2006.12.017

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The CO2 reforming of methane on the Rh/Al2O3 catalyst was performed using a flow microreactor at 773-973 K. The effects of the catalyst pretreatment, the ratio of CH4/CO2 and the CeO2 support were studied. The oxidized/reduced Rh/Al2O3 catalyst had a higher activity and the addition Of CO2 significantly enhanced the CH4 reforming to form H-2 and reduced the catalyst deactivation caused by carbon deposition on the active sites. The Rh/CeO2 catalyst was less active during the CH4 reforming with CO2 addition than the Rh/Al2O3 catalyst based on the catalyst weight, whereas the areal activity of Rh/CeO2 was close to Rh/Al2O3. (c) 2007 Published by Elsevier Ltd.

引用

页码：4998 / 5000

页数：3

共 5 条

[1] Promoting effect of Pt, Pd and Rh noble metals to the Ni0.03Mg0.97O solid solution catalysts for the reforming of CH4 with CO2 [J].