Absolute asymmetric photocyclization in chiral diarylethene co-crystals with octafluoronaphthalene

被引：33

作者：

Morimoto, Masakazu ^{[1
,2
]}

Kobatake, Seiya ^{[2
,3
]}

Irie, Masahiro ^{[1
]}

机构：

[1] Rikkyo Univ, Dept Chem, Toshima Ku, Tokyo 1718501, Japan

[2] Japan Sci & Technol Agcy, Precursory Res Embryon Sci & Technol, Kawaguchi, Saitama 3320012, Japan

[3] Osaka City Univ, Grad Sch Engn, Dept Appl Chem, Sumiyoshi Ku, Osaka 5588585, Japan

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 03期

关键词：

D O I：

10.1039/b713694c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A photochromic diarylethene containing naphthyl groups formed a chiral crystal when co-crystallized with octafluoronaphthalene, although both molecules are achiral, and underwent highly enantioselective photocyclization owing to the conformational confinement in the crystal.

引用

页码：335 / 337

页数：3

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