Crystal structure and a new phase transition of (ND4)(3)D(SO4)(2) in high temperature phase

被引：16

作者：

Fukami, T ^{[1
]}

Ninomiya, H ^{[1
]}

Chen, RH ^{[1
]}

机构：

[1] NATL TAIWAN NORMAL UNIV,DEPT PHYS,TAIPEI 11718,TAIWAN

来源：

SOLID STATE IONICS | 1997年 / 98卷 / 1-2期

关键词：

(ND4)(3)D(SO4)(2); crystal structure; phase I; proton conductor; new phase transition; electric conductivity; x-ray diffraction;

D O I：

10.1016/S0167-2738(97)00105-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electric conductivity and X-ray diffraction measurements are performed on deuterated triammonium hydrogen disulphate (ND4)(3)D(SO4)(2) in high temperature phase. A new structural phase transition that corresponds to the transition at 463 K of (NH4)(3)H(SO4)(2) is found at 413 K. The space group symmetry (monoclinic C2) and the crystal structure of (ND4)(3)D(SO4)(2) are determined at 404 K in phase I. The electric conductivity due to the deuterium ion migration in phase I is discussed with respect to the results of the structure refinement.

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页码：105 / 111

页数：7

相关论文

共 20 条

[1] FAST PROTON TRANSPORT IN CRYSTALS WITH A DYNAMICALLY DISORDERED HYDROGEN-BOND NETWORK [J].

BARANOV, AI ;

MERINOV, BV ;

TREGUBCHENKO, AV ;

KHIZNICHENKO, VP ;

SHUVALOV, LA ;

SCHAGINA, NM .

SOLID STATE IONICS, 1989, 36 (3-4) :279-282

[2] STRUCTURAL STUDY OF THE HIGH AND LOW-TEMPERATURE PHASES OF THE PROTON CONDUCTOR RB3H(SEO4)(2) [J].

BOHN, A ;

MELZER, R ;

SONNTAG, R ;

LECHNER, RE ;

SCHUCK, G ;

LANGER, K .

SOLID STATE IONICS, 1995, 77 :111-117

[3] X-RAY STUDY ON THE PHASE-TRANSITIONS IN TRIAMMONIUM HYDROGEN DISULFATE CRYSTALS AND DEUTERATED CRYSTALS [J].

CHEN, RH ;

WANG, LM ;

YANG, SC .

PHASE TRANSITIONS, 1992, 37 (2-3) :141-147

[4] VO2+ ELECTRON-PARAMAGNETIC-RES STUDIES ON PHASE-TRANSITIONS IN (NH4)3H(SO4)2 CRYSTALS [J].

FUJIMOTO, M ;

SINHA, BV .

FERROELECTRICS, 1983, 46 (3-4) :227-244

[5] A NEW PHASE-TRANSITION OF (NH4)3H(SO4)2 AT 190-DEGREES-C [J].

FUKAMI, T ;

TOBARU, K ;

KANEDA, K ;

NAKASONE, K ;

FURUKAWA, K .

JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1994, 63 (05) :2006-2007

[6] Crystal structure of (NH4)(3)H(SO4)(2) in phase I [J].

Fukami, T ;

Horiuchi, K ;

Nakasone, K ;

Furukawa, K .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1996, 35 (4A) :2253-2254

[7] DIELECTRIC STUDY ON THE EFFECT OF HYDROSTATIC-PRESSURE ON THE PHASE-TRANSITIONS IN THE SYSTEM OF ((NH4)3H(SO4)2)1-X(ND4)3D(SO4)2)X [J].

GESI, K ;

OZAWA, K ;

OSAKA, T ;

MAKITA, Y .

JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1980, 49 (03) :1083-1089

[8] DIELECTRIC STUDY ON PHASE-TRANSITIONS IN TRIAMMONIUM HYDROGEN DISULFATE (NH-4)3H(SO-4)2 [J].

GESI, K .

PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1976, 33 (02) :479-482

[9] PRESSURE-INDUCED FERROELECTRICITY IN (NH4)H(SO4)2-H-3 [J].

GESI, K .

JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1977, 43 (06) :1941-1948

[10] II-]III PHASE-TRANSITIONS IN TRIAMMONIUM HYDROGEN DISULFATE (NH4)3H(SO4)2 [J].

KAMOUN, M ;

BENGHOZLEN, MH ;

DAOUD, A .

PHASE TRANSITIONS, 1987, 9 (03) :247-252