1,3,5-tris(4-aminophenyl) benzene derivatives:: design, synthesis via nickel-catalysed aromatic amination and electrochemical properties

被引：5

作者：

Desmarets, C

Schneider, R

Fort, Y

Walcarius, A

机构：

[1] Univ Nancy 1, CNRS, Fac Sci, UMR 7565, F-54506 Vandoeuvre Les Nancy, France

[2] Univ Nancy 1, CNRS, UMR 7564, Lab Chim Phys & Microbiol Environm, F-54600 Villers Les Nancy, France

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 2002年 / 11期

关键词：

D O I：

10.1039/b206689k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Nickel-catalysed polycondensation reactions of 1,3,5-tris(p-chlorophenyl) benzene with secondary cyclic and acyclic amines afforded the corresponding triarylamines in good yields. Oxidation of these materials creates dications diradicals that are stable over several minutes at room temperature. The electronic and magnetic properties of these dications were investigated by cyclic voltammetry, chronoamperometry, UV-VIS and EPR spectroscopy.

引用

页码：1844 / 1849

页数：6

共 17 条

[1] New efficient nickey(0) catalysed amination of aryl chlorides
Brenner, E
Fort, Y
[J]. TETRAHEDRON LETTERS, 1998, 39 (30) : 5359 - 5362
[2] ORGANIC ELECTRON-TRANSFER SYSTEMS .2. SUBSTITUTED TRIARYLAMINE CATION-RADICAL REDOX SYSTEMS - SYNTHESIS, ELECTROCHEMICAL AND SPECTROSCOPIC PROPERTIES, HAMMET BEHAVIOR, AND SUITABILITY AS REDOX CATALYSTS
DAPPERHELD, S
STECKHAN, E
BRINKHAUS, KHG
ESCH, T
[J]. CHEMISCHE BERICHTE, 1991, 124 (11) : 2557 - 2567
[3] PHENYLIODINE(III) BIS(TRIFLUOROACETATE) AS A RADICAL-CATION GENERATING REAGENT
EBERSON, L
HARTSHORN, MP
PERSSON, O
[J]. ACTA CHEMICA SCANDINAVICA, 1995, 49 (09): : 640 - 644
[4] FLEXIBLE LIGHT-EMITTING-DIODES MADE FROM SOLUBLE CONDUCTING POLYMERS
GUSTAFSSON, G
CAO, Y
TREACY, GM
KLAVETTER, F
COLANERI, N
HEEGER, AJ
[J]. NATURE, 1992, 357 (6378) : 477 - 479
[5] Hartmann H, 2001, ANGEW CHEM INT EDIT, V40, P552, DOI 10.1002/1521-3773(20010202)40:3<552::AID-ANIE552>3.0.CO
[6] 2-C
[7] Heinze J, 2001, ANGEW CHEM INT EDIT, V40, P2861, DOI 10.1002/1521-3773(20010803)40:15<2861::AID-ANIE2861>3.0.CO
[8] 2-T
[9] Triplet state of WUrster's blue-based di(cation radical)
Ito, A
Taniguchi, A
Yamabe, T
Tanaka, K
[J]. ORGANIC LETTERS, 1999, 1 (05) : 741 - 743
[10] PERFORMANCE STUDY OF AQUEOUS POLYANILINE BATTERIES
KITANI, A
KAYA, M
SASAKI, K
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1986, 133 (06) : 1069 - 1073

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