Thermodynamics of the neutral-to-ionic transition as condensation and crystallization of charge-transfer excitations

被引:127
作者
LemeeCailleau, MH
LeCointe, M
Cailleau, H
Luty, T
Moussa, F
Roos, J
Brinkmann, D
Toudic, B
Ayache, C
Karl, N
机构
[1] WROCLAW TECH UNIV,INST PHYS & THEORET CHEM,PL-50370 WROCLAW,POLAND
[2] CEA SACLAY,CNRS,LAB LEON BRILLOUIN,F-91191 GIF SUR YVETTE,FRANCE
[3] UNIV ZURICH,INST PHYS,CH-8057 ZURICH,SWITZERLAND
[4] CEN,LAB CRYOPHYS,F-38041 GRENOBLE,FRANCE
[5] UNIV STUTTGART,INST PHYS,D-70550 STUTTGART,GERMANY
关键词
D O I
10.1103/PhysRevLett.79.1690
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The pressure-temperature phase diagram of tetrathiafulvalene-p-chloranil, prototype for the neutral-to-ionic transition, is determined by neutron diffraction and nuclear quadrupole resonance and discussed in relation to thermally induced charge-transfer (CT) excitations. The respective role of ionicity and dimerization is highlighted. Supported by theoretical considerations taking into account the interplay between quantum and thermal effects, the experimental results show that this uncommon electronic-structural transition can be described in terms of condensation and crystallization of CT excitations with a solid-liquid-gas-like phase diagram.
引用
收藏
页码:1690 / 1693
页数:4
相关论文
共 28 条
[1]   ISING MODEL FOR LAMBDA TRANSITION AND PHASE SEPARATION IN HE-3-HE-4 MIXTURES [J].
BLUME, M ;
EMERGY, VJ ;
GRIFFITHS, RB .
PHYSICAL REVIEW A-GENERAL PHYSICS, 1971, 4 (03) :1071-+
[2]   CHLORINE-NUCLEAR-QUADRUPOLE-RESONANCE STUDY OF THE NEUTRAL-TO-IONIC TRANSITION IN TETRATHIAFULVALENE-CHLORANIL [J].
GALLIER, J ;
TOUDIC, B ;
DELUGEARD, Y ;
CAILLEAU, H ;
GOURDJI, M ;
PENEAU, A ;
GUIBE, L .
PHYSICAL REVIEW B, 1993, 47 (18) :11688-11695
[3]   VIBRATIONAL SPECTROSCOPY OF MIXED STACK ORGANIC SEMICONDUCTORS - NEUTRAL AND IONIC PHASES OF TETRATHIAFULVALENE CHLORANIL (TTF-CA) CHARGE-TRANSFER COMPLEX [J].
GIRLANDO, A ;
MARZOLA, F ;
PECILE, C ;
TORRANCE, JB .
JOURNAL OF CHEMICAL PHYSICS, 1983, 79 (02) :1075-1085
[4]   GROUND-STATE OPTICAL-PROPERTIES OF CHARGE-TRANSFER CRYSTALS CLOSE TO THE NEUTRAL-IONIC INTERFACE - TETRATHIAFULVALENE-2,5-DICHLORO-P-BENZOQUINONE [J].
GIRLANDO, A ;
PAINELLI, A ;
PECILE, C ;
CALESTANI, G ;
RIZZOLI, C ;
METZGER, RM .
JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (10) :7692-7698
[5]   RAMAN-STUDY OF THE PRESSURE-INDUCED NEUTRAL-TO-IONIC TRANSITION IN TETRATHIAFULVALENE CHLORANIL [J].
HANFLAND, M ;
BRILLANTE, A ;
GIRLANDO, A ;
SYASSEN, K .
PHYSICAL REVIEW B, 1988, 38 (02) :1456-1461
[6]   The role of long-range Coulomb interaction in the neutral-to-ionic transition of quasi-one-dimensional charge transfer compounds [J].
IizukaSakano, T ;
Toyozawa, Y .
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1996, 65 (03) :671-674
[7]   BEHAVIOR OF CHARGE-TRANSFER ABSORPTION UPON PASSING THROUGH THE NEUTRAL-IONIC PHASE-TRANSITION [J].
JACOBSEN, CS ;
TORRANCE, JB .
JOURNAL OF CHEMICAL PHYSICS, 1983, 78 (01) :112-115
[8]   OPTICAL REFLECTIVITY SPECTRA OF THE MIXED-STACK ORGANIC CHARGE-TRANSFER CRYSTAL TETRATHIAFULVALENE-PARA-CHLORANIL UNDER HYDROSTATIC-PRESSURE [J].
KANEKO, Y ;
TANUMA, S ;
TOKURA, Y ;
KODA, T ;
MITANI, T ;
SAITO, G .
PHYSICAL REVIEW B, 1987, 35 (15) :8024-8029
[9]   First-principles molecular-dynamics simulations for neutral p-chloranil and its radical anion [J].
Katan, C ;
Blochl, PE ;
Margl, P ;
Koenig, C .
PHYSICAL REVIEW B, 1996, 53 (18) :12112-12120
[10]   PHOTOINDUCED VALENCE INSTABILITY IN THE ORGANIC MOLECULAR-COMPOUND TETRATHIAFULVALENE-P-CHLORANIL (TTF-CA) [J].
KOSHIHARA, S ;
TOKURA, Y ;
MITANI, T ;
SAITO, G ;
KODA, T .
PHYSICAL REVIEW B, 1990, 42 (10) :6853-6856