Synthesis of fused polycyclic aromatics by palladium-catalyzed annulation of arynes using 2-halobiaryls

被引：152

作者：

Liu, ZJ ^{[1
]}

Zhang, XX ^{[1
]}

Larock, RC ^{[1
]}

机构：

[1] Iowa State Univ, Dept Chem, Ames, IA 50011 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 45期

关键词：

D O I：

10.1021/ja055781o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Pd-catalyzed annulation of arynes by 2-halobiaryls and related vinylic halides provides a very efficient, high yielding synthesis of polycyclic aromatic and heteroaromatic hydrocarbons. This process appears to involve the catalytic, stepwise coupling of two very reactive substrates, an aryne and an organopalladium species, to generate excellent yields of cross-coupled products. Copyright © 2005 American Chemical Society.

引用

页码：15716 / 15717

页数：2

共 23 条

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