Peroxynitrite: A Re-examination of the Chemical Properties of Non-thermal Discharges Burning in Air Over Aqueous Solutions

被引：140

作者：

Brisset, Jean-Louis ^{[1
]}

Hnatiuc, Eugen ^{[2
]}

机构：

[1] Univ Rouen, Fac Sci, F-76821 Mont St Aignan, France

[2] Univ Apollonia Iasi, Iasi, Romania

来源：

PLASMA CHEMISTRY AND PLASMA PROCESSING | 2012年 / 32卷 / 04期

关键词：

Cold plasma; Reactive nitrogen species; Acid effects; Transient nitrite; Peroxynitrite; GLIDING-ARC; PLASMA TREATMENT; RATE CONSTANTS; CHEMISTRY; NO; HYDROGEN; REACTORS;

D O I：

10.1007/s11090-012-9384-x

中图分类号：

TQ [化学工业];

学科分类号：

081705 [工业催化];

摘要：

The main compounds of non-thermal plasmas generated by a discharge in humid air at atmospheric pressure are re-examined to explain the twin chemical properties of discharges over aqueous waste solutions, i.e. the acid and oxidizing effects. The acid effects are attributed to transient nitrous and peroxynitrous acids and to stable nitric acid. The matching oxidizing power of the discharge species onto solutes is due to water soluble H2O2 provided by the dimer formation of A degrees OH and also to peroxynitrous acid ONOOH and its salt which are involved in the oxidation process of nitrous to nitric acid.

引用

页码：655 / 674

页数：20

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