Structural and thermal studies of [PVA-LiAc]:TiO2 polymer nanocomposite system

被引:9
作者
Tripathi, Mridula [1 ]
Trivedi, Shivangi [1 ]
Dhar, Ravindra [2 ]
Singh, Markandey [3 ]
Pandey, N. D. [4 ]
Agrawal, S. L. [3 ]
机构
[1] Univ Allahabad, Dept Chem, CMP Degree Coll, Allahabad 211002, Uttar Pradesh, India
[2] Univ Allahabad, Ctr Mat Sci, Allahabad 211002, Uttar Pradesh, India
[3] APS Univ, Dept Phys, Rewa, India
[4] MNNIT, Dept Chem, Allahabad, Uttar Pradesh, India
关键词
nanocomposite; polymer electrolyte; X-ray diffraction; scanning electron microscopy; ION-TRANSPORT; PROTON; CONDUCTIVITY;
D O I
10.1080/01411594.2011.573456
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Nanocomposite polymer electrolyte consisting of polyvinyl alcohol (PVA) and lithium acetate with TiO2 filler has been synthesised by combination of solution cast technique and sol-gel process. The composite electrolyte films were characterised by different experimental techniques. The average particle size of composite electrolytes lies between 25 and 30 nm. System is essentially ionic with maximum conductivity of polymer electrolyte 90[80PVA-20LiAc]:10TiO(2) (similar to 4.5 x 10(-6) S cm(-1)) at room temperature.
引用
收藏
页码:972 / 980
页数:9
相关论文
共 27 条
[1]   Dielectric investigations in PVA based gel electrolytes [J].
Awadhia, Arvind ;
Patel, S. K. ;
Agrawal, S. L. .
PROGRESS IN CRYSTAL GROWTH AND CHARACTERIZATION OF MATERIALS, 2006, 52 (1-2) :61-68
[2]  
Aziz NAN, 2010, INT J PHYS SCI, V5, P748
[3]  
Chandra S., 1981, SUPERIONIC SOLIDS PR
[4]  
Cullity Bernard D., 1978, Elements of X-Ray Diffraction
[5]   The photopolymerization and characterization of methyl methacrylate initiated by nanosized titanium dioxide [J].
Dong, C ;
Ni, XY .
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 2004, A41 (05) :547-563
[6]   DOUBLE ORIENTATION AND INFRA-RED DICHROISM IN POLYMERS [J].
ELLIOTT, A ;
AMBROSE, EJ ;
TEMPLE, RB .
NATURE, 1949, 163 (4145) :567-567
[7]  
Fragiadakis D., 2008, J MACROMOLECULES, V41, P5723
[8]   Studies on all solid state electric double layer capacitors using proton and lithium ion conducting polymer electrolytes [J].
Hashmi, SA ;
Latham, RJ ;
Linford, RG ;
Schlindwein, WS .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1997, 93 (23) :4177-4182
[9]  
MacCallum J.R. V., 1987, POLYM ELECTROLYTE RE
[10]  
Mukherjee GS, 2004, J SCI IND RES INDIA, V63, P596