A facile route to semiconductor nanocrystal-semiconducting polymer complex using amine-functionalized rod-coil triblock copolymer as multidentate ligand

被引:28
作者
Fang, Chun
Qi, Xiao-Ying
Fan, Qu-Li [1 ]
Wang, Lian-Hui
Huang, Wei
机构
[1] Fudan Univ, Inst Adv Mat, Shanghai 200433, Peoples R China
[2] Nanjing Univ Posts & Telecommun, Inst Adv Mat, Shanghai 210003, Peoples R China
关键词
D O I
10.1088/0957-4484/18/3/035704
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A facile strategy affording an intimate nanocomplex of an amine-containing rod-coil triblock copolymer poly(2-(dimethylamino)ethylmethacrylate)-poly(fluorene)-poly(2-(dimethyl amino) ethylmethacrylate) and CdSe nanocrystals is presented. Ligand exchange is observed by P-31 NMR. TEM and UV-vis absorption results indicate the CdSe NCs have a good dispersion in the conjugated polymer. Also, the PL spectra show photoinduced charge transfer has been facilitated by the complex formation.
引用
收藏
页数:5
相关论文
共 39 条
[1]   Efficient excitation transfer from polymer to nanocrystals [J].
Chang, TWF ;
Musikhin, S ;
Bakueva, L ;
Levina, L ;
Hines, MA ;
Cyr, PW ;
Sargent, EH .
APPLIED PHYSICS LETTERS, 2004, 84 (21) :4295-4297
[2]  
COLVIN VL, 1994, NATURE, V370, P354, DOI 10.1038/370354a0
[3]   ELECTROLUMINESCENCE FROM CDSE QUANTUM-DOT POLYMER COMPOSITES [J].
DABBOUSI, BO ;
BAWENDI, MG ;
ONITSUKA, O ;
RUBNER, MF .
APPLIED PHYSICS LETTERS, 1995, 66 (11) :1316-1318
[4]   Electroluminescence studies on self-assembled films of PPV and CdSe nanoparticles [J].
Gao, MY ;
Richter, B ;
Kirstein, S ;
Mohwald, H .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (21) :4096-4103
[5]   Electrochemical synthesis of CdTe nanocrystal/polypyrrole composites for optoelectronic applications [J].
Gaponik, NP ;
Talapin, DV ;
Rogach, AL ;
Eychmüller, A .
JOURNAL OF MATERIALS CHEMISTRY, 2000, 10 (09) :2163-2166
[6]   Photoinduced electron transfer from conjugated polymers to CdSe nanocrystals [J].
Ginger, DS ;
Greenham, NC .
PHYSICAL REVIEW B, 1999, 59 (16) :10622-10629
[7]   Charge separation and transport in conjugated-polymer/semiconductor-nanocrystal composites studied by photoluminescence quenching and photoconductivity [J].
Greenham, NC ;
Peng, XG ;
Alivisatos, AP .
PHYSICAL REVIEW B, 1996, 54 (24) :17628-17637
[8]   Exciton diffusion and dissociation in a poly(p-phenylenevinylene)/C-60 heterojunction photovoltaic cell [J].
Halls, JJM ;
Pichler, K ;
Friend, RH ;
Moratti, SC ;
Holmes, AB .
APPLIED PHYSICS LETTERS, 1996, 68 (22) :3120-3122
[9]   EFFICIENT PHOTODIODES FROM INTERPENETRATING POLYMER NETWORKS [J].
HALLS, JJM ;
WALSH, CA ;
GREENHAM, NC ;
MARSEGLIA, EA ;
FRIEND, RH ;
MORATTI, SC ;
HOLMES, AB .
NATURE, 1995, 376 (6540) :498-500
[10]   Hybrid nanorod-polymer solar cells [J].
Huynh, WU ;
Dittmer, JJ ;
Alivisatos, AP .
SCIENCE, 2002, 295 (5564) :2425-2427