Synthesis, structure, and electrochemical properties of new ''unsymmetrical'' metal dithiolate complexes

被引：37

作者：

Kato, R ^{[1
]}

Kashimura, Y ^{[1
]}

Sawa, H ^{[1
]}

Okano, Y ^{[1
]}

机构：

[1] CHIBA UNIV, FAC SCI, DEPT PHYS, INAGE KU, CHIBA 263, JAPAN

来源：

CHEMISTRY LETTERS | 1997年 / 09期

关键词：

D O I：

10.1246/cl.1997.921

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New ''unsymmetrical'' (mixed ligand) metal dithiolate complexes, expected as components of molecular conductors, have been obtained by a ligand-exchange reaction in refluxing acetone, followed by isolation with a preparative HPLC (ODP; acetonitrile-H2O). Their electrochemical data suggest that the acceptor (donor) ability and the on-site Coulomb energy for the ''unsymmetrical'' complexes can be tuned by a combination of ligands.

引用

页码：921 / 922

页数：2

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