Dehydrogenation of methyl-cyclohexane under multiphase reaction conditions

被引：37

作者：

Zhang, Liyan ^{[1
]}

Xu, Guohua ^{[1
]}

An, Yue ^{[1
]}

Chen, ChangPin ^{[1
]}

Wang, Qidong ^{[1
]}

机构：

[1] Zhejiang Univ, Coll Mat Sci & Chem Engn, Hangzhou 310027, Peoples R China

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2006年 / 31卷 / 15期

关键词：

methyl-cyclohexane; dehydrogenation; Raney-Ni; multiphase condition;

D O I：

10.1016/j.ijhydene.2006.02.001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Dehydrogenation of methyl-cyclohexane (MCH) catalyzed by Raney-Ni under a multiphase reaction condition was studied in this paper. The evolved gases were continuously separated from the reaction system through a condenser during the reaction, and the influences of the reaction temperatures (483-573 K), the amounts of the reactant (0.2-4.0 ml) feed and the catalyst (2-10 g) dosages on the conversion had been investigated. The mechanism of the multiphase reaction was analyzed from the viewpoints of the dynamic energy balance. Our experimental results showed that there existed an optimal energy balance point, which guaranteed not only the efficient contact between the reactant and catalyst, but also the higher conversion of the MCH dehydrogenation. At 523 K, with 0.5 ml MCH amount feed and 8 g Raney-Ni dosages, the dehydrogenation conversion of MCH could reach similar to 65%. (c) 2006 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.

引用

页码：2250 / 2255

页数：6

共 16 条

[1] Hydrogen absorption properties of the slurry system composed of liquid C6H6 and F-treated Mg2Ni [J].

Chen, CP ;

Cai, GM ;

Chen, Y ;

An, Y ;

Xu, GH ;

Wang, QD .

JOURNAL OF ALLOYS AND COMPOUNDS, 2003, 350 (1-2) :275-279

[2]

GUANMING C, 2002, J RARE EARTH, V20, P28

[3]

HUAJUN Y, 2004, J RARE EARTH, V22, P385

[4]

HUAJUN Y, 2004, THESIS ZHEJIANG U HA

[5] A MEMBRANE REACTOR USING PALLADIUM [J].

ITOH, N .

AICHE JOURNAL, 1987, 33 (09) :1576-1578

[6] BASIC EXPERIMENTAL-STUDY ON PALLADIUM MEMBRANE REACTORS [J].

ITOH, N ;

XU, WC ;

HARAYA, K .

JOURNAL OF MEMBRANE SCIENCE, 1992, 66 (2-3) :149-155

[7]

JIWEN Z, 2005, THESIS ZHEJIANG U HA

[8]

KAIYA N, 2003, APPL CATAL A-GEN, V247, P247

[9]

KAIYA N, 2002, APPL CATAL A-GEN, V233, P91

[10]

SHIYAO D, 2003, J CHEM ENG CHIN U, V17, P9

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