Sulfur resistance and high activity of hydrated manganese sulfate in the catalytic oxidation of methanethiol

被引：15

作者：

Cellier, C ^{[1
]}

Gaigneaux, EM ^{[1
]}

Grange, P ^{[1
]}

机构：

[1] Univ Catholique Louvain, Univ Catalyse & Chim Mat Divises, B-1348 Louvain, Belgium

来源：

JOURNAL OF CATALYSIS | 2004年 / 222卷 / 01期

关键词：

metal sulfate catalyst; oxidation; hydration; sulfur resistance;

D O I：

10.1016/j.jcat.2003.10.029

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydration of manganese sulfate at a low reaction temperature (150 degreesC) induces high heterogeneous catalytic activity and stability in the oxidation of methanethiol. The temperature of the reaction controls the reversible change of structure, i.e., hydration/dehydration processes as well as the associated changes of activity and selectivity. (C) 2003 Elsevier Inc. All rights reserved.

引用

页码：255 / 259

页数：5

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